Potassium Hydroxide → HCID 16679760, Verbindung

Reaktionsgleichung

[C:1]([S:5][CH2:6][C:7]1([CH3:14])[NH:11][C:10](=[O:12])[NH:9][C:8]1=[O:13])([CH3:4])([CH3:3])[CH3:2].[OH-:15].[K+]>>[C:10]([NH:11][C@:7]([CH3:14])([C:8]([OH:15])=[O:13])[CH2:6][S:5][C:1]([CH3:4])([CH3:3])[CH3:2])(=[O:12])[NH2:9]

Komponenten

Edukt 2

HCID 14797Potassium Hydroxide

HCID 11195294HCID 11195294, Verbindung

Produkt 1

HCID 16679760HCID 16679760, VerbindungAusbeute 92 %

Reaktionsbedingungen

Temperatur: 95 °C

Versuchsvorschrift

First, 5-tert-butylthiomethyl-5-methylhydantoin (5 g, 23 mmol) was mixed with a 58% aqueous potassium hydroxide solution (9.2 g), and the mixture was heated to 95° C. and stirred for 22 hours. The HPLC analysis of the reaction solution showed the production of the title compound in a reaction yield of 92%.