2-Mesityl-3-nitropyridine → 2-Mesityl-3-pyridinamine

HRID 890192

Reaktionsgleichung

Reaktionsgleichung von HRID 890192
[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([N+:15]([O-])=O)=[CH:13][CH:12]=[CH:11][N:10]=1>[H][H].[C].[Pd]>[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([NH2:15])=[CH:13][CH:12]=[CH:11][N:10]=1

Komponenten

4

Edukt 1

HCID 222494912-Mesityl-3-nitropyridine

Produkt 1

HCID 167414262-Mesityl-3-pyridinamineAusbeute 106,5 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178418390HCID 178418390, VerbindungKatalysatorHCID 178418361HCID 178418361, VerbindungLösungsmittel

Versuchsvorschrift

Palladium-carbon (10%, 0.6 g) was added to a solution of 2-mesityl-3-nitropyridine (5.99 g, 23 mmol) methanol (120 mL), followed by stirring for one day in hydrogen atmospher. The mixture was filtered through Celite and evaporated, to give the title compound (5.2 g) as white crystals.

Aufarbeitung

  1. filtrationThe mixture was filtered through Celite
  2. customevaporated

Quellen und Nachweise

ORD-Eintrag
ord-3915ad166a144395be4ef2b92973d110
Quelldatensatz
uspto-grants-2006_02
Patentnummer
US06995163B2

Verknüpfte Notizen

Wird geladen…