Potassium Iodide → Methyl 2-acetylheptanoate
Reaktionsgleichung
[CH3:1][O:2][C:3](=[O:8])/[CH:4]=[C:5](/[O-:7])\[CH3:6].[Na+].[I-].[K+].[CH2:12](Br)[CH2:13][CH2:14][CH2:15][CH3:16]>>[C:5]([CH:4]([CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[C:3]([O:2][CH3:1])=[O:8])(=[O:7])[CH3:6]Komponenten
4
Versuchsvorschrift
Analogously to Example 14A, 30 g (217 mmol) of sodium (2E)-4-methoxy-4-oxo-2-buten-2-olate (Example 13A) and 1.24 g (7.5 mmol) of potassium iodide are reacted with 32.8 g (217 mmol) of n-pentyl bromide to give methyl 2-acetylheptanoate.
Quellen und Nachweise
- ORD-Eintrag
- ord-3218440b62ef4668817da9c97c355450
- Quelldatensatz
- uspto-grants-2006_02
- Patentnummer
- US06998402B2
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