Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | tert-Butyl hydroperoxide | HCID 6410 | — |
| Edukt | 1-Octene | HCID 8125 | — |
| Edukt | Potassium Acetate | HCID 517044 | — |
| Lösungsmittel | Acetic Acid | HCID 176 | — |
| Produkt | alpha-Hexyl-gamma-butyrolactone | HCID 86736 | 65% |
Reaktionsschritte
A stock solution was prepared by heating at 115° C. 500 milliliters of acetic acid, 150 grams of potassium acetate, and 245 grams of manganous acetate tetrahydrate, Mn(OCOCH3)2.4H2O. A 50-milliliter aliquot of the stock solution was added to 2 milliliters of a 0.312 molar solution of tertiary butyl hydroperoxide in acetic acid. The solution also contained 400 microliters of octene-1. After heating, a hexyl gamma-butyrolactone was obtained with a 65% yield based on the tertiary butyl hydroperoxide.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US04285868 |
|---|
| Quelldatensatz | uspto-grants-1981_08 |
|---|
| ORD ID | ord-b50eee57f5ae47179765aab26f16a942 |
|---|
| Quellennotiz | uspto-grants-1981_08 |
|---|
