HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Triethylamine → N'-hydroxynonanimidamide
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Triethylamine | HCID 8471 | — |
| Edukt | Nonanenitrile | HCID 16715 | — |
| Edukt | Hydroxyamine hydrochloride | HCID 443297 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | N'-hydroxynonanimidamide | HCID 5074022 | 27% |
Reaktionsschritte
Octyl cyanide (2 g, 14 mmol) and hydroxylamine hydrochloride (2.495 g, 36 mmol) were dissolved in EtOH (10 mL) and treated with triethylamine (5 mL, 36 mmol) at reflux over night. Extraction: AcOEt/water. Silica gel chromatography: heptane/AcOEt 1:2 afforded a white solid (0.65 g, 26%). MS: m/z=173 (M +H).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07351700B2 |
| Quelldatensatz | uspto-grants-2008_04 |
| ORD ID | ord-344e2ede1a55402092f36b2c52f6ed11 |
| Quellennotiz | uspto-grants-2008_04 |