HCID 11676128, Verbindung → HCID 58711714, Verbindung
Reaktionsgleichung
C(OC([C@@H:7]1[CH2:12][CH2:11][N:10]([CH2:13][C:14]2[CH:23]=[CH:22][CH:21]=[C:20]3[C:15]=2[C:16]([NH:24][C:25]2[CH:30]=[CH:29][CH:28]=[C:27]([C:31]#[CH:32])[CH:26]=2)=[N:17][CH:18]=[N:19]3)[CH2:9][C@@H:8]1[C:33]([O:35][CH3:36])=[O:34])=O)C=C.[NH2:37][C@@H]1CCN(CC2C=CC=C3C=2C(NC2C=CC=C(OC)C=2)=NC=N3)C[C@H]1C(NC)=O>CO>[NH2:37][C@@H:7]1[CH2:12][CH2:11][N:10]([CH2:13][C:14]2[CH:23]=[CH:22][CH:21]=[C:20]3[C:15]=2[C:16]([NH:24][C:25]2[CH:30]=[CH:29][CH:28]=[C:27]([C:31]#[CH:32])[CH:26]=2)=[N:17][CH:18]=[N:19]3)[CH2:9][C@H:8]1[C:33]([O:35][CH3:36])=[O:34]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
Compound 18B was prepared from 18A in a similar way as 15F. It has an analytical HPLC retention time=1.546 min (Chromolith SpeedROD column 4.6×50 mm, 10-90% aqueous methanol containing 0.1% TFA over 4 minutes, 4 mL/min, monitoring at 254 nm) and a LC/MS M++H=416+.