Octane → 4-Octanol

Reaktionsgleichung

[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].CC([OH:17])CCCCCC.CCC(O)CCCCC>>[CH3:1][CH2:2][CH2:3][CH:4]([OH:17])[CH2:5][CH2:6][CH2:7][CH3:8]

Komponenten

Edukt 3

HCID 356Octane

HCID 115273-Octanol

HCID 200832-Octanol

Produkt 1

HCID 115154-Octanol

Versuchsvorschrift

A further selective hydroxylation reaction was carried out with the sol-gel-embedded CYP BM-3 on the substrate n-octane. 79% of the precursor were hydroxylated. The regio isomers 2-octanol, 3-octanol and 4-octanol were obtained in a molar ratio of 1:2.1:1.6 (detected by gas chromatography).

Aufarbeitung

customA further selective hydroxylation reaction

Quellen und Nachweise

ORD-Eintrag: ord-20c3b18d9f184c1f8e49d48beccdc67d
Quelldatensatz: uspto-grants-2008_04
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US07364884B2

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