HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- → Tetracyanoquinodimethane
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- | HCID 73696 | — |
| Katalysator | HCID 178418406 | HCID 178418406 | — |
| Lösungsmittel | Toluene | HCID 1140 | — |
| Produkt | Tetracyanoquinodimethane | HCID 73697 | — |
Reaktionsschritte
According to the procedure of Fatiadi Synthesis, 1976, 133, incorporated herein by reference, the 1,4-bis(dicyanomethylene)cyclohexane is allowed to react with manganese dioxide in refluxing (110° C.) toluene for ca. 15 minutes to provide TCNQ in ca. 60% yields.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04229364 |
| Quelldatensatz | uspto-grants-1980_10 |
| ORD ID | ord-366e9c2a0e504e51b09d96e9e5139ab7 |
| Quellennotiz | uspto-grants-1980_10 |