Zurück
HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 904338Erstellt: 25. Oktober 2026

2,4-Bis(1,1-dimethylethyl)-6-[2-(2-nitrophenyl)diazenyl]phenol → 2-(2'-Hydroxy-3'5-di-tert-butylphenyl) benzotriazole

https://huagongshe.com/reaction/904338

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt2,4-Bis(1,1-dimethylethyl)-6-[2-(2-nitrophenyl)diazenyl]phenolHCID 104110—
KatalysatorPalladiumHCID 23938—
LösungsmittelIsopropanol triethylamineHCID 21183856—
Produkt2-(2'-Hydroxy-3'5-di-tert-butylphenyl) benzotriazoleHCID 7745577%

Reaktionsschritte

When using the general procedure of Example 5, a 23% by weight suspension of 2-nitro-2'-hydroxy-3',5'-di-tert-butylazobenzene in isopropanol/triethylamine (1/0.18) was hydrogenated at 45° C. at 1 atmosphere pressure for 3 hours in the presence of 3% of a 5% palladium on charcoal catalyst the above noted product was obtained in a yield of 77%.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04230867
Quelldatensatzuspto-grants-1980_10
ORD IDord-6db687a322b24b6da166884f270153dc
Quellennotizuspto-grants-1980_10