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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 908116Erstellt: 26. Oktober 2026

Methyl {4-[4-(2-bromo-2-methylpropanoyl)phenyl]bicyclo[2.2.2]oct-1-yl}acetate → Methyl {3-[4-(2-bromo-2-methylpropanoyl)phenyl]-1-adamantyl}acetate

https://huagongshe.com/reaction/908116

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktMethyl {4-[4-(2-bromo-2-methylpropanoyl)phenyl]bicyclo[2.2.2]oct-1-yl}acetateHCID 25258107—
EduktMethyl 3-phenyl-1-adamantaneacetateHCID 53665692—
ProduktMethyl {3-[4-(2-bromo-2-methylpropanoyl)phenyl]-1-adamantyl}acetateHCID 5937978635%

Reaktionsschritte

Prepared according to the procedure described for Intermediate 9 using methyl (3-phenyl-1-adamantyl)acetate, the title compound being isolated in 35% yield: 1H NMR (CDCl3) δ 1.66 (d, 4H), 1.71 (s, 2H), 1.77 (s, 2H), 1.87 (s, 4H), 2.04 (s, 6H), 2.18 (s, 2H), 2.20-2.22 (m, 2H), 3.65 (s, 3H), 7.41 (d, 2H), 8.12 (d, 2H); GC-MS CI m/e MH+ 433.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS08017603B2
Quelldatensatzuspto-grants-2011_09
ORD IDord-e06bc9ffd35a49d4a9b7925493953fdf
Quellennotizuspto-grants-2011_09