2,6-Dipropylphenol → 2,6-Dipropyl4-propionylphenol

HRID 9250Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 9250
[C:1]([O-:5])(=O)[CH2:2][CH3:3].[Na+].[CH2:7]([C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([CH2:16][CH2:17][CH3:18])[C:11]=1[OH:19])[CH2:8][CH3:9]>OS(C(F)(F)F)(=O)=O>[CH2:16]([C:12]1[CH:13]=[C:14]([C:1](=[O:5])[CH2:2][CH3:3])[CH:15]=[C:10]([CH2:7][CH2:8][CH3:9])[C:11]=1[OH:19])[CH2:17][CH3:18]

Komponenten

4

Edukt 2

HCID 811072,6-DipropylphenolHCID 2723816Sodium Propionate

Produkt 1

HCID 113108722,6-Dipropyl4-propionylphenol

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 62406Trifluoromethanesulfonic acidLösungsmittel

Versuchsvorschrift

Sodium propanoate (0.88 g, 1.5 eq) and 2,6-dipropylphenol (1.09 g, 1.0 eq) were combined in Triflic Acid (5.0 g) as in Example 13, step 1. The resulting waxy solid was purified by chromatography on silica gel using ethyl acetate:hexanes:acetic acid (10:90:1) to give the titled phenol.

Aufarbeitung

  1. customThe resulting waxy solid was purified by chromatography on silica gel

Quellen und Nachweise

ORD-Eintrag
ord-ec11d9e4f3f449f6a915145c8ea66bec
Quelldatensatz
uspto-grants-2006_08
Patentnummer
US07091230B2

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