5-(Dimethylamino)-N-(2-oxoethyl)naphthalene-1-sulfonamide → HCID 86710866, Verbindung
Reaktionsgleichung
C([O:3][CH:4](OCC)[CH2:5][CH2:6][CH2:7][NH:8][S:9]([C:12]1[C:21]2[C:16](=[C:17]([N:22]([CH3:24])[CH3:23])[CH:18]=[CH:19][CH:20]=2)[CH:15]=[CH:14][CH:13]=1)(=[O:11])=[O:10])C.O=CCNS(C1C2C(=C(N(C)C)C=CC=2)C=CC=1)(=O)=O.COC(OC)CNS(C1C2C(=C(N(C)C)C=CC=2)C=CC=1)(=O)=O>>[O:3]=[CH:4][CH2:5][CH2:6][CH2:7][NH:8][S:9]([C:12]1[C:21]2[C:16](=[C:17]([N:22]([CH3:24])[CH3:23])[CH:18]=[CH:19][CH:20]=2)[CH:15]=[CH:14][CH:13]=1)(=[O:11])=[O:10]Komponenten
4
Versuchsvorschrift
This aldehyde was prepared from acetal 13 at a scale and under conditions identical to those employed for the preparation N-(2-oxoethyl)-5-(dimethylamino)naphthalene-1-sulfonamide from acetal 11. N-(4-Oxobutyl)-5-(dimethylamino)naphthalene-1-sulfonamide was obtained as a light green foam, the total amount of which was used without further purification in the preparation of 14.