Diglycerin → Diglycerol mono-ricinoleate diglycerol di-ricinoleate
Reaktionsgleichung
C(O)C(O)C[O:4][CH2:5][CH:6]([OH:9])[CH2:7][OH:8].[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24]>>[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9].[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24].[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9]Komponenten
3
Versuchsvorschrift
From table 7a it appears that for esters of diglycerol and ricinoleic acid optimum wearing reduction is provided with a molar ratio diglycerol mono-ricinoleate/diglycerol di-ricinoleate of about 1.15.
Quellen und Nachweise
- ORD-Eintrag
- ord-b586272e42a149a2b3adcc042b4fbcde
- Quelldatensatz
- uspto-grants-2016_03
- Patentnummer
- US09290434B2