Propargyl bromide → 4-[(2-Propynyloxy)methyl]benzyl alcohol
Reaktionsgleichung
[OH:1][CH2:2][C:3]1[CH:10]=[CH:9][C:6]([CH2:7][OH:8])=[CH:5][CH:4]=1.[CH2:11](Br)[C:12]#[CH:13]>>[CH2:13]([O:1][CH2:2][C:3]1[CH:10]=[CH:9][C:6]([CH2:7][OH:8])=[CH:5][CH:4]=1)[C:12]#[CH:11]Komponenten
3
Versuchsvorschrift
In an analogous manner to that described in Example 1, from 4-(hydroxymethyl)benzyl alcohol and propargyl bromide there is obtained 4-[(2-propynyloxy)methyl]benzyl alcohol. This alcohol is reacted in an analogous manner to that described in Example 2 with cyclopropane carboxylic acid chloride to give cyclopropane carboxylic acid p-[(2-propynyloxy)methyl]benzyl ester.
Quellen und Nachweise
- ORD-Eintrag
- ord-4012781ca93f49b08510409f1f36f07c
- Quelldatensatz
- uspto-grants-1979_07
- Patentnummer
- US04162328
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