Triethylamine → HCID 178513470, Verbindung

HRID 972290

Reaktionsgleichung

Reaktionsgleichung von HRID 972290
[N+:1]([C:4]1[CH:15]=[CH:14][C:7]([CH:8]=[CH:9][S:10](Cl)(=[O:12])=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[N+:16]([C:19]1[CH:27]=[CH:26][C:22]([C:23]([NH2:25])=[NH:24])=[CH:21][CH:20]=1)([O-:18])=[O:17].C(N(CC)CC)C>CC(C)=O>[N+:1]([C:4]1[CH:15]=[CH:14][C:7]([CH:8]=[CH:9][S:10]([NH:25][C:23](=[NH:24])[C:22]2[CH:21]=[CH:20][C:19]([N+:16]([O-:18])=[O:17])=[CH:27][CH:26]=2)(=[O:12])=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2]

Komponenten

5

Edukt 3

HCID 8471TriethylamineHCID 1174754-NitrobenzamidineHCID 3480064-Nitrostyrylsulfonyl chloride

Produkt 1

HCID 178513470HCID 178513470, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 180AcetoneLösungsmittel

Versuchsvorschrift

4-Nitrostyrylsulfonyl chloride (2.5 g., 0.01 mole) is added portion-wise to a solution of 4-nitrobenzamidine (1.65 g., 0.01 mole), prepared according to the procedure of L. Weintraub, et al., J. Org. Chem., 33, 1979 (1968), and triethylamine (1.01 g., 0.01 mole) in 50 ml. of acetone at 10° C. After stirring for a period of 1 hr. at 25° C., the mixture is concentrated under reduced pressure and the residual material stirred with water and collected. Triturating the filter cake with acetone provides N-(4-NITROSTYRYLSULFONYL)-4-NITROBENZAMIDINE, m.p. 173°-177° C.

Aufarbeitung

  1. customprepared
  2. customat 10° C
  3. concentrationat 25° C., the mixture is concentrated under reduced pressure
  4. stirringthe residual material stirred with water
  5. customcollected
  6. customTriturating the filter cake with acetone

Quellen und Nachweise

ORD-Eintrag
ord-7924d363f13b4dfc9ce29d5cb78f9c05
Quelldatensatz
uspto-grants-1977_10
Patentnummer
US04052455

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