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Copper(II) oxalate → Copper(II) oxalate

HRID 972464
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 972464
[Mo:1](=O)(=O)=[O:2].C.C1(N)N=C(N)N=C(N)N=1.C1(N)N=C(N)N=C(N)N=1.[C:24]([O-:29])(=[O:28])[C:25]([O-:27])=[O:26].[Cu+2:30].C1C(=O)N(Br)C(=O)C1>>[Mo:1]=[O:2].[C:24]([O-:29])(=[O:28])[C:25]([O-:27])=[O:26].[Cu+2:30]
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Komponenten

6

Edukt 4

HCID 13148Copper(II) oxalateHCID 14802Molybdenum trioxideHCID 67184N-bromobutanimideHCID 103335Molybdate (Mo2O72-), hydrogen, compd. with 1,3,5-triazine-2,4,6-triamine (1:2:1)

Produkt 2

HCID 13148Copper(II) oxalateHCID 139765Molybdenum oxide

Versuchsvorschrift

When molybdenum trioxide is substituted for the melamine molybdate in combination with the copper oxalate in the above compound, no practical synergism is noted with this combination. For example, in the flaming mode NBS smoke test Dm /g values of about 23 (58.8% smoke reduction relative to the standard compound of Example I) were obtained with ratios of 1.0 molybdenum oxide and 4.0 copper oxalate, 2.0 molybdenum oxide and 3.0 copper oxalate, 3.0 molybdenum oxide and 2.0 copper oxalate, 4.0 molybdenum oxide and 1.0 copper oxalate. In contrast, it should be noted that when 1.0 copper oxalate and 4.0 melamine molybdate were used in the same compound the Dm /g was 19.08 with a smoke reduction of 65.1%, and with 4.0 copper oxalate and 1.0 melamine molybdate the Dm /g was 19.92 and a 64.38% smoke reduction.

Quellen und Nachweise

ORD-Eintrag
ord-eed27a03226344f3961a5d7f29d55a3b
Quelldatensatz
uspto-grants-1977_10
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US04053453

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