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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 9750Erstellt: 23. Oktober 2026

Oxygen → 4-Chlorobenzoic Acid

https://huagongshe.com/de/reaction/9750

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktOxygenHCID 977—
Edukt4-ChlorotolueneHCID 7810—
Edukt1,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trioneHCID 10419723—
KatalysatorCobalt diacetateHCID 6277—
LösungsmittelAcetic AcidHCID 176—
Produkt4-Chlorobenzoic AcidHCID 6318—
Produkt4-ChlorotolueneHCID 7810—

Reaktionsschritte

A mixture of 0.380 g of 4-chlorotoluene, 0.027 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (5% by mole relative to 4-chlorotoluene), 5 g of acetic acid and 0.004 g of cobalt(II) acetate.4H2O was stirred at 100° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 14 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield 4-chlorobenzoic acid in 99% yield at 100% conversion of 4-chlorotoluene.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS07091342B2
Quelldatensatzuspto-grants-2006_08
ORD IDord-c6a8ba3d36bf4f319c6bd44ce0526ecd
Quellennotizuspto-grants-2006_08