HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Oxygen → 4-Chlorobenzoic Acid
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Oxygen | HCID 977 | — |
| Edukt | 4-Chlorotoluene | HCID 7810 | — |
| Edukt | 1,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trione | HCID 10419723 | — |
| Katalysator | Cobalt diacetate | HCID 6277 | — |
| Lösungsmittel | Acetic Acid | HCID 176 | — |
| Produkt | 4-Chlorobenzoic Acid | HCID 6318 | — |
| Produkt | 4-Chlorotoluene | HCID 7810 | — |
Reaktionsschritte
A mixture of 0.380 g of 4-chlorotoluene, 0.027 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (5% by mole relative to 4-chlorotoluene), 5 g of acetic acid and 0.004 g of cobalt(II) acetate.4H2O was stirred at 100° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 14 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield 4-chlorobenzoic acid in 99% yield at 100% conversion of 4-chlorotoluene.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07091342B2 |
| Quelldatensatz | uspto-grants-2006_08 |
| ORD ID | ord-c6a8ba3d36bf4f319c6bd44ce0526ecd |
| Quellennotiz | uspto-grants-2006_08 |