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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 9751Erstellt: 23. Oktober 2026

Oxygen → Benzaldehyde

https://huagongshe.com/de/reaction/9751

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktOxygenHCID 977—
EduktTolueneHCID 1140—
Edukt1,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trioneHCID 10419723—
KatalysatorCobalt diacetateHCID 6277—
LösungsmittelAcetic AcidHCID 176—
ProduktBenzaldehydeHCID 240—
ProduktBenzoic AcidHCID 243—

Reaktionsschritte

A mixture of 0.276 g of toluene, 0.005 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (1% by mole relative to toluene), 5 g of acetic acid and 0.004 g of cobalt(II) acetate.4H2O was stirred at 60° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 6 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield benzoic acid and benzaldehyde in 49% and 3% yields, respectively, at 53% conversion of toluene.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS07091342B2
Quelldatensatzuspto-grants-2006_08
ORD IDord-25be29cbfe4341219e0e5c16fc46daa6
Quellennotizuspto-grants-2006_08