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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 975191Erstellt: 23. Oktober 2026

1,2-Benzenedicarbonitrile, 4-nitro- → 4-Phenoxyphthalonitrile

https://huagongshe.com/de/reaction/975191

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt1,2-Benzenedicarbonitrile, 4-nitro-HCID 97443—
EduktPhenolate SodiumHCID 4445035—
LösungsmittelDimethylformamideHCID 6228—
Produkt4-PhenoxyphthalonitrileHCID 37180049%

Reaktionsschritte

The procedure of Example 35 was followed except that 1,2-dicyano-4nitrobenzene (1.0 part) was used in place of the 1,2-dicyano-3-nitrobenzene, 1.0 parts instead of 2.79 parts of sodium phenoxide and 20 parts instead of 50 parts of dimethylformamide were used. 1,2-Dicyano-4-phenoxybenzene (0.6 parts, 49%) was obtained as a white solid, m.pt.98°-100° C.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05608053
Quelldatensatzuspto-grants-1997_03
ORD IDord-19c265b2bcc344db835c87a5c17bfb81
Quellennotizuspto-grants-1997_03