HCID 474761, Verbindung → HCID 178465648, Verbindung

HRID 978607Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 978607
[C:1](=[N:9][NH2:10])([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][N:4]=1)[CH3:2].[C:11]1([N:17]=[C:18]=[Se:19])[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>CC#N>[C:11]1([NH:17][C:18]([NH:10][N:9]=[C:1]([C:3]2[CH:8]=[CH:7][CH:6]=[CH:5][N:4]=2)[CH3:2])=[Se:19])[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

Komponenten

4

Edukt 2

HCID 474761HCID 474761, VerbindungHCID 555335HCID 555335, Verbindung

Produkt 1

HCID 178465648HCID 178465648, VerbindungAusbeute 45 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6342AcetonitrileLösungsmittel

Reaktionsbedingungen

Temperatur
45 °C

Versuchsvorschrift

To a solution of 2.6 g (20 mmol) of 2-acetylpyridine hydrazone in 25 ml of CH3CN was added 3.6 g (20 mmol) of phenylisoselenocyanate. The clear red solution was heated with stirring to 45° C. for 3 hours, the solution was cooled to room temperature, and the crystals which separated were collected. Recrystallization of the product from EtOH gave 2.83 g (45%) of N-phenyl-2-[1-(2-pyridinyl)ethylidene]hydrazinecarboselenoamide as fine yellow needles, mp 153°-156° C.

Aufarbeitung

  1. temperatureThe clear red solution was heated
  2. temperaturethe solution was cooled to room temperature
  3. customthe crystals which separated
  4. customwere collected
  5. customRecrystallization of the product from EtOH

Quellen und Nachweise

ORD-Eintrag
ord-7ba25266a9e64c2380f2a0623e665226
Quelldatensatz
uspto-grants-1987_05
Patentnummer
US04665173

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