HCID 21621270, Verbindung → HCID 87126116, Verbindung

HRID 979263Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 979263
C[O:2][C:3](=[O:22])[CH2:4][CH2:5][O:6][N:7]([CH2:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C[Si](C)(C)[O-].[K+:28]>C1(C)C=CC=CC=1>[K+:28].[CH2:15]([N:7]([CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[O:6][CH2:5][CH2:4][C:3]([O-:22])=[O:2])[C:16]1[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=1

Komponenten

4

Edukt 2

HCID 21621270HCID 21621270, VerbindungHCID 23668039Potassium trimethylsilanolate

Produkt 1

HCID 87126116HCID 87126116, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Versuchsvorschrift

To a stirred solution of 9.75 g of the compound of Example I in 100 ml of toluene is added 3.85 g of potassium trimethylsilanolate. After stirring the mixture at room temperature for 12 hours, the mixture is concentrated under reduced pressure and the residue is triturated with ether to leave the title compound as an off-white hygroscopic solid.

Aufarbeitung

  1. concentrationthe mixture is concentrated under reduced pressure
  2. customthe residue is triturated with ether

Quellen und Nachweise

ORD-Eintrag
ord-e09a25c6a02a4ae192969210919bf411
Quelldatensatz
uspto-grants-1987_05
Patentnummer
US04666962

Notizen zur Reaktion

Wird geladen…