HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Ammonia → 2-{Bicyclo[2.2.1]heptan-2-yl}ethan-1-amine
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Ammonia | HCID 222 | — |
| Edukt | Thionyl Chloride | HCID 24386 | — |
| Edukt | Norborn-2-ylacetic acid | HCID 79139 | — |
| Edukt | Aluminium lithium hydride | HCID 21226445 | — |
| Produkt | 2-{Bicyclo[2.2.1]heptan-2-yl}ethan-1-amine | HCID 20222870 | 35% |
Reaktionsschritte
Norbornane-2-acetic acid was treated with SOCl2, then with NH3. The resulting amine was reduced with LiAlH4 to give the desired intermediate. Yield: 35%.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04634701 |
| Quelldatensatz | uspto-grants-1987_01 |
| ORD ID | ord-89ff04e69db24ab5aa91db85b2fdded3 |
| Quellennotiz | uspto-grants-1987_01 |