Hydroxyacetonitrile → (Dodecylamino)acetonitrile

HRID 980862

Reaktionsgleichung

Reaktionsgleichung von HRID 980862
O[CH2:2][C:3]#[N:4].[CH2:5]([NH2:17])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>CO>[CH2:5]([NH:17][CH2:2][C:3]#[N:4])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Komponenten

4

Edukt 2

HCID 7857HydroxyacetonitrileHCID 13583Dodecylamine

Produkt 1

HCID 222308(Dodecylamino)acetonitrile

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

In a flask of 500 ml provided with a magnetic stirrer, 4.56 gr of hydroxyacetonitrile (0.08 mol) were mixed at room temperature with 16.3 gr of dodecylamine (0.088 mol) in 250 ml of methanol. The mixture was allowed to stand for 16 hours at room temperature and methanol was evaporated. The obtained liquid was distilled under 10-2 mm Hg. The fraction distilling between 106° and 116° crystallizes after cooling.

Aufarbeitung

  1. customIn a flask of 500 ml provided with a magnetic stirrer
  2. custommethanol was evaporated
  3. distillationThe obtained liquid was distilled under 10-2 mm Hg
  4. distillationThe fraction distilling between 106° and 116°
  5. customcrystallizes
  6. temperatureafter cooling

Quellen und Nachweise

ORD-Eintrag
ord-062b5b872d41428695569fdb5abf608a
Quelldatensatz
uspto-grants-1987_01
Patentnummer
US04639468

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