2-Buten-1-amine, 3-methyl- → HCID 178446447, Verbindung

HRID 982293

Reaktionsgleichung

Reaktionsgleichung von HRID 982293
[CH3:1][C:2]([CH3:6])=[CH:3][CH2:4][NH2:5].C[N:8](N=O)[C:9]([NH:11][N+:12]([O-:14])=[O:13])=N>CCO.O>[CH3:1][C:2]([CH3:6])=[CH:3][CH2:4][NH:5][C:9]([NH:11][N+:12]([O-:14])=[O:13])=[NH:8]

Komponenten

4

Edukt 2

HCID 1669212-Buten-1-amine, 3-methyl-HCID 135436526N-Methyl-N'-nitro-N-nitrosoguanidine

Produkt 1

HCID 178446447HCID 178446447, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 19096565Water ethanolLösungsmittel

Versuchsvorschrift

3-methyl-2-butenylamine (3.0 g) is added dropwise at room temperature to a slurry of 1-methyl-3-nitro-1 -nitrosoguanidine (4.3 g) in 50 ml of EtOH/H2O (1/1). After stirring the mixture at room temperature for 18 hours, the precipitate which forms is removed by filtration. The solid is then slurred with dilute hydrochloric acid, collected by filtration and washed with ethanol/water (30/70). Recrystallization from ethanol gives a white solid with mp 134°-136° C.

Aufarbeitung

  1. customthe precipitate which forms is removed by filtration
  2. filtrationcollected by filtration
  3. washwashed with ethanol/water (30/70)
  4. customRecrystallization from ethanol
  5. customgives a white solid with mp 134°-136° C.

Quellen und Nachweise

ORD-Eintrag
ord-fc1345d0539b41a2bec5e144a8d474e9
Quelldatensatz
uspto-grants-1991_02
Patentnummer
US04995903

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