1-Bromohexadecane → HCID 15141162, Verbindung

HRID 987347Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 987347
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].[OH:18][C:19]1[CH:20]=[C:21]([CH:24]=[C:25]([OH:28])[C:26]=1[OH:27])[CH:22]=[O:23]>>[CH2:2]([O:18][C:19]1[CH:20]=[C:21]([CH:24]=[C:25]([O:28][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2])[C:26]=1[O:27][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2])[CH:22]=[O:23])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

Komponenten

3

Edukt 2

HCID 82131-BromohexadecaneHCID 836513,4,5-Trihydroxybenzaldehyde

Produkt 1

HCID 15141162HCID 15141162, Verbindung

Versuchsvorschrift

The title compound was prepared according to the method as described in Example 9 above from 1-bromohexadecane and 3,4,5-trihydroxy-benzaldehyde, except the reaction mixture was heated at reflux for 4 days. After cooling, the solid material was removed by filtration and the solid washed with dichloromethane. The combined organic extracts were evaporated under reduced pressure to yield the title compound which was recrystallised from dichloromethane-ethanol.

Aufarbeitung

  1. customThe title compound was prepared
  2. temperaturewas heated
  3. temperatureat reflux for 4 days
  4. temperatureAfter cooling
  5. customthe solid material was removed by filtration
  6. washthe solid washed with dichloromethane
  7. customThe combined organic extracts were evaporated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-4081cdd73fc04656868dbfaefafb1f6a
Quelldatensatz
uspto-grants-2003_10
Patentnummer
US06630128B1

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