Pyrrole → 5-[4-(12-Acetyloxy-dodecyloxy)-phenyl]-10,15,20-tris-(3,5-dihexyloxy-phenyl)-porphyrin

HRID 987351

Reaktionsgleichung

Reaktionsgleichung von HRID 987351
[CH2:1]([O:7][C:8]1[CH:9]=[C:10]([CH:13]=[C:14]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH:15]=1)[CH:11]=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH:23]([C:25]1[CH:47]=[CH:46][C:28]([O:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][O:42][C:43](=[O:45])[CH3:44])=[CH:27][CH:26]=1)=O.[NH:48]1[CH:52]=[CH:51][CH:50]=[CH:49]1>>[C:43]([O:42][CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][O:29][C:28]1[CH:46]=[CH:47][C:25]([C:23]2[C:52]3[NH:48][C:49]([C:11]([C:10]4[CH:13]=[C:14]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH:15]=[C:8]([O:7][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6])[CH:9]=4)=[C:49]4[N:48]=[C:52]([C:11]([C:10]5[CH:13]=[C:14]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH:15]=[C:8]([O:7][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6])[CH:9]=5)=[C:52]5[NH:48][C:49](=[C:11]([C:10]6[CH:9]=[C:8]([O:7][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6])[CH:15]=[C:14]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH:13]=6)[C:49]6[CH:50]=[CH:51][C:52]=2[N:48]=6)[CH:50]=[CH:51]5)[CH:51]=[CH:50]4)=[CH:50][CH:51]=3)=[CH:26][CH:27]=1)(=[O:45])[CH3:44]

Komponenten

4

Edukt 3

HCID 8027PyrroleHCID 11244987Acetic Acid 12-(4-Formyl-phenoxy)-dodecyl EsterHCID 229875513,5-Bis(hexyloxy)benzaldehyde

Produkt 1

HCID 1363883585-[4-(12-Acetyloxy-dodecyloxy)-phenyl]-10,15,20-tris-(3,5-dihexyloxy-phenyl)-porphyrin

Versuchsvorschrift

The title compound was prepared according to the method described in Example 15 above from 3,5-dihexyloxy-benzaldehyde (see Example 12), acetic acid 12-(4-formyl-phenoxy)-dodecyl ester (see Example 6) and pyrrole.

Quellen und Nachweise

ORD-Eintrag
ord-d94ba5009aa04e4c8b1c14679feb185f
Quelldatensatz
uspto-grants-2003_10
Patentnummer
US06630128B1

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