HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Adamantane → 1-Nitroadamantane
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Adamantane | HCID 9238 | — |
| Edukt | N-Hydroxyphthalimide | HCID 10665 | — |
| Edukt | Nitric Oxide | HCID 145068 | — |
| Edukt | Nitrogen Dioxide | HCID 178526396 | — |
| Lösungsmittel | Acetic Acid | HCID 176 | — |
| Lösungsmittel | Benzonitrile | HCID 7505 | — |
| Produkt | 1-Adamantanol | HCID 64152 | 6% |
| Produkt | 1-Nitroadamantane | HCID 64165 | 68% |
Reaktionsschritte
Into a flask, 1 mmole of adamantane, 0.1 mmole of N-hydroxyphthalimide, 2 ml of nitrogen dioxide (N2O), 6 ml of benzonitrile (6 ml) and 1.2 ml of acetic acid were added and stirred for 12 hours at 60° C. in an atmosphere of nitrogen monoxide (NO). The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 98%, nitroadamantane (yield 68%), adamantanol (yield 6%) and acetyloxyadamantane (yield 4%) were formed.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06468487B1 |
| Quelldatensatz | uspto-grants-2002_10 |
| ORD ID | ord-21b5cc6f392b455aa5422c0c24119d5f |
| Quellennotiz | uspto-grants-2002_10 |