HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Oxygen → 1-Nitroadamantane
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Oxygen | HCID 977 | — |
| Edukt | (Trifluoromethyl)benzene | HCID 7368 | — |
| Edukt | Adamantane | HCID 9238 | — |
| Edukt | N-Hydroxyphthalimide | HCID 10665 | — |
| Edukt | Nitrogen Dioxide | HCID 178526396 | — |
| Lösungsmittel | Acetonitrile | HCID 6342 | — |
| Produkt | 1-Adamantanol | HCID 64152 | 2% |
| Produkt | 1-Nitroadamantane | HCID 64165 | 73% |
| Produkt | 1-Adamantyl acetate | HCID 519973 | 1% |
Reaktionsschritte
Into a flask, 1 mmole of adamantane, 0.05 mmole of N-hydroxyphthalimide, 15 mmole of nitrogen dioxide (NO2), 1 ml of acetonitrile and 2 ml of trifluoromethylbenzene were added and stirred for 5 hours at 60° C. in an atmosphere of oxygen. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 90%, and nitroadamantane (yield 73%), adamantanol (yield 2%), acetyloxyadamantane (yield 1%) and adamantanone (yield 3%) were formed.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06468487B1 |
| Quelldatensatz | uspto-grants-2002_10 |
| ORD ID | ord-684f6da515db4ca99b2f29e56dd22d9f |
| Quellennotiz | uspto-grants-2002_10 |