Basic information
- CAS
762-99-2- Standard SMILES
CC(C)O.CC(C)O.[Cl][Ti][Cl]- InChIKey
CGWFOWZGURYLHA-UHFFFAOYSA-L- Molecular formula
- C6H16Cl2O2Ti
- Average molar mass
- 238.96 g/mol
- Monoisotopic mass
- 238.000676
Names & identifiers
- Preferred name
- Dichlorotitanium;propan-2-ol
- IUPAC
- dichlorotitanium;bis(propan-2-ol)
- English name
- Dichlorotitanium diisopropoxide
- Molecular formula
- C6H14Cl2O2Ti
- Molecular weight
- 236.95
Names & synonyms
dichlorotitanium;propan-2-olTiCl2(Oi-Pr)2SCHEMBL477445Dichlorobis(propan-2-olato)titaniumEINECS 212-106-6CS-0086069DICHLORO(DIISOPROPOXY)TITANIUMDiisopropoxytitanium(IV) ChlorideDichlorotitanium diisopropoxideDichlorotitaniumDiisopropoxide>dichlorobis(propan-2-olato)titaniumTitanium,dichlorobis(2-propanolato)-, (T-4)-
Database identifiers
- CAS
762-99-2- PubChem CID
- 101855
Properties
Computed structural properties
- Topological polar surface area
- 40.5 Ų
- Hydrogen bond donors
- 2
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 0
- Heavy atoms
- 11
- Formal charge
- 0
- Complexity
- 47.8
Physicochemical properties
- Melting point
- 42 · 42-43 °C
- storage temp.
- Freezer
- solubility
- 2 Cl2, · sol CH2Cl2, toluene, and other solvents.
- form
- powder to crystal
- color
- White to Light yellow
- EPA Substance Registry System
- Titanium, dichlorobis(2-propanolato)-, (T-4)- (762-99-2)
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319
- Precautionary statements
- 264 · P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
- Risk Statements
- 36 · 36/37/38
- Safety Statements
- 26 · 26-36/37/39
- TSCA
- TSCA listed
- HS Code
- 2931.9 · 2931.90.9051
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- tsca
- TSCA listed
- hs_code
- 2931.90.9051
- risk_code
- 36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- safety_code
- 26-36/37/39
- Hazard statements
- H315-H319
- Precautionary statements
- P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Chemistry & industry
Applications
UsesDichlorotitanium diisopropoxide is a Lewis acid frequently used in the preparation of chiral titanium complexes; an efficient catalyst for Diels-Alder reactions, [2 + 2] cycloadditions, and carbonyl-ene reactions, including asymmetric versions of these processes; a reagent for titanium enolate formation; and a catalyst component for the stereoselective addition of cyanide and allyltin nucleophiles to aldehydes.
Preparation methods
PreparationDichlorotitanium diisopropoxide is prepared by adding slowly at rt an equimolar amount of Titanium(IV) Chloride to a hexane solution of Titanium Tetraisopropoxide; following mixing, during which heat is evolved, the mixture is allowed to stand at rt for 6 h and the precipitate is collected and washed with hexane; dibromotitanium diisopropoxide is prepared similarly.
Suppliers31 total
国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
Aladdin Scientific[email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
Loading…