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Hartshorn salt

HCID 10480
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
506-87-6
Standard SMILES
N.N.O=C(O)O
InChIKey
PRKQVKDSMLBJBJ-UHFFFAOYSA-N
Molecular formula
CH8N2O3
Average molar mass
96.09 g/mol
Monoisotopic mass
96.05349212

Overview

See also: Ammonium Carbonate (preferred); Carbonate Ion (has active moiety); Emvita 8 (FDA NDC: 66343-095) (component of) ... View More ...

Names & identifiers

Preferred name
Hartshorn salt
IUPAC
azane;carbonic acid
English name
Ammonium carbonate
Molecular formula
CH8N2O3
Molecular weight
96.09

Names & synonyms

Hartshorn saltCaswell No. 042Ammoniumcarbonat [German]CCRIS 7328Carbonate d'ammoniaque [French]HSDB 6305EINECS 208-058-0EPA Pesticide Chemical Code 073501AI3-25347Ammonium carbonate solutionUNII-PDP691CN28MFCD00010890
Show more names
(NH4)2CO3GlucitolcrystalammoniaКарбонат аммония, Аммониевая соль угольной кислоты, Ammonium carbonate, Diammonium carbonatehartshornBROMOCRESOL GREammoniumcarbonatAmmonium carboteSALT OF HARTSHORN
EC 208-058-0diamine carbonateammonia;carbonic acidSCHEMBL510CH8N2O3AMMONIUM CARBONATE [MI]CHEMBL2105849SCHEMBL10894453

Database identifiers

CAS
506-87-6
PubChem CID
10480
ChEMBL
CHEMBL2105849
UNII
PDP691CN28

Properties

Computed structural properties

Topological polar surface area
59.5 Ų
Hydrogen bond donors
4
Hydrogen bond acceptors
5
Rotatable bonds
0
Heavy atoms
6
Formal charge
0
Complexity
26.3

Physicochemical properties

Melting point
58 °C · 58 °C
Boiling point
179.58 °C · 179.58°C (rough estimate)
Density
1.5 · 1.5
vapor density
2.7 · 2.7 (vs air)
vapor pressure
760 mm · 760 mm Hg @ 600C
refractive index
1.4616 · 1.4616 (estimate)
storage temp.
Store at RT.
solubility
2 O: · H2O: 0.1 g/mL at 25 °C, clear, colorless
form
Solid
color
White to yellow
Odor
3 · strong odor of NH3
PH Range
9 · 9
Water Solubility
SOLUBLE
Sensitive
Hygroscopic
Merck
14 · 14,508
BRN
3627235 · 3627235
Cosmetic Ingredient Review (CIR)
Ammonium carbonate (506-87-6)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

F
13
wgk
1
tsca
TSCA listed
rtecs
BP1925000
ridadr
UN 9084
hs_code
28369940
Toxicity
LD50 ivn-mus: 96 mg/kg AJVRAH 29,897,68
risk_code
22-52/53
Signal word
Warning
Symbol(GHS)
GHS07
hazard_code
Xn
safety_code
24/25
hazard_class
9
Storage Class
11 - Combustible Solids
Hazard statements
H302
Limited Quantities
5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations
Active
Precautionary statements
P301+P312+P330
Hazardous Substances Data
506-87-6(Hazardous Substances Data)

Chemistry & industry

Applications · 6 items

UsesIt is used as raw material for baking powder, various ammonium salts, buffer agent, auxiliaries, fertilizer and analytical reagent. Edible ammonium carbonate is used as buffer, neutralizing agent, leavening agent, fermentation promoter (manufacture of wine). It is used for fire fighting, detergents, and used in medicine, rubber, and other industrial fermentation. The above information is edited by the chemicalbook of Wang Xiaodong.

DescriptionAmmonium carbonate is an inorganic herbicide, fungicide and biocide. It is non-volatile and highly soluble in water. Ammonium acetate has a low mammalian toxicity and there is some risk of bioaccumulation. It is a recognised irritant. Ecotoxicological data is scarce.

UsesAmmonium Carbonate is a dough strengthener, a leavening agent, a ph control agent, and a texturizer. it is prepared by the sublima- tion of a mixture of ammonium sulfate and calcium carbonate, and occurs as a white powder or a hard, white translucent mass.

UsesPharmaceutic aid (source of ammonia).

UsesAmmonium carbonate is widely utilized as a leavening agent in lebkuchen, cookies and flat biscuits. It finds an important application as an emetic and an active ingredient in some cough syrups. It is the main component in smelling salts and an active ingredient in some smokeless tobacco products, shampoos and dyes used in textile industries. It is an important predecessor to the modern leavening agents baking soda and baking powder. It serves as a foaming agent for the production of expanded material. It is also used as a reagent for analytical purposes in the chemical industry.

General DescriptionA colorless crystalline solid or a white powder with a strong odor of ammonia. Noncombustible. The primary hazard is the threat to the environment. Immediate steps should be taken to limit spread to the environment. Used to make other ammonium compounds, in pharmaceuticals, in food processing.

Preparation methods · 1 item

PreparationAmmonium carbonate is obtained by passing carbon dioxide into aqueous ammonia solution in a column or tower. Ammonia, carbon dioxide and water vapor are distilled and the vapors condensed into a solid crystalline mass. It also may be prepared by subliming a mixture of ammonium sulfate and calcium carbonate.

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
InChI
1S/CH2O3.2H3N/c2-1(3)4;;/h(H2,2,3,4);2*1H3
InChIKey
PRKQVKDSMLBJBJ-UHFFFAOYSA-N
SMILES
N.N.OC(O)=O
LogP
-0.809 · -0.809 (est)
CAS DataBase Reference
506 · 506-87-6(CAS DataBase Reference)
FDA 21 CFR
184.1137 · 184.1137; 582.1137
EWG's Food Scores
1 · 1
FDA UNII
691 CN28 · PDP691CN28
EPA Substance Registry System
Ammonium carbonate (506-87-6)
UNSPSC Code
12352301 · 12352301
NACRES
55 · NA.55
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
302 · H302
Precautionary statements
301 · P301+P312+P330
Hazard Codes
Xn
Risk Statements
22 · 22-52/53
Safety Statements
24 · 24/25
RIDADR
9084 · UN 9084
WGK Germany
1 · 1
RTECS
1925000 · BP1925000
F
13 · 13
TSCA
TSCA listed
HazardClass
9 · 9
HS Code
28369940 · 28369940
Storage Class
11 · 11 - Combustible Solids
Hazardous Substances Data
506 · 506-87-6(Hazardous Substances Data)
Toxicity
50 ivn-mus: · LD50 ivn-mus: 96 mg/kg AJVRAH 29,897,68
REACH Registrations
Active
Limited Quantities
5 kg · 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Upstream & downstream products

Upstream raw materials

Ammonium hydroxideCarbon dioxideAmmonium bicarbonateAmmonia

Downstream products

MephenytoinStrontium carbonateLuminol2,5-Dimethyl-1H-pyrroleBarium carbonateAmmonium L-tartrate4-BromobenzenesulfonamideL-ValineAcetamide4-Amino-5-bromo-2-methylpyridine4-Sulfamoylphenylboronic acid, pinacol esterAmmonium sulfamatemedium temperature Shift catalysts5,5-DimethylhydantoinGlycineTrimebutine maleateCupferronL-glutamic acid monoammoniumBenzamideCARAMELmedium(high)temperature Shift catalystsQuinalphos

Suppliers100 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
合肥翰刚医药科技有限公司+8618062405514 · [email protected]
上海光铧科技有限公司13801626616 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
Hebei Yanxi Chemical Co., Ltd.+86-17531190177 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
武汉卡诺斯科技有限公司027-83238443 15327105076 · [email protected]
济南飞越化工有限公司18615221057 · [email protected]
北京绿百草科技发展有限公司010-61136123 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
上海景颜化工科技有限公司13817811078 · [email protected]
上海泰坦科技股份有限公司4006009262 13023226327 · [email protected]
武汉丰泰威远科技有限公司+86-27-8746-5837 +86-18627785180 · [email protected]
武汉丰泰威远科技有限公司027-87465837 19945049750 · [email protected]
天津金汇太亚化学试剂有限公司022-59582624 18622766592 · [email protected]
上海竺钥化工有限公司021-33559231 18964673308 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
南京化学试剂股份有限公司025-58369808 17895012682 · [email protected]
武汉吉业升化工有限公司027-13545242311 13545242311 · [email protected]
斯百全化学(上海)有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
艾科试剂4008-755-333 18080918076 · [email protected]
赛默飞世尔科技(中国)有限公司800-810-5118 · [email protected]
北京伊诺凯科技有限公司400-810-7969 010-59572699 · [email protected]
上海遐瑞医药科技有限公司+86 21 61551611
北京环宇世纪化学科技有限公司hysj_bj.com
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]
上海将来实业股份有限公司021-61552785 · [email protected]
HBCChem, Inc.+1-510-219-6317 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
成都润泽本土化工有限公司13096311329 028-88469284 616445927 · [email protected]
湖北巨胜科技有限公司027-59599241 18871490274 · [email protected]
池州凯隆进出口贸易有限公司[email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
南京六方意化工有限公司19956514532 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
上海博熠生物医药科技有限公司021-021-54331997 18321536537 · [email protected]
杭州鼎燕化工有限公司0571-87157530-8003 18049756717 · [email protected]
厦门志信化学有限公司+86-5922680277 +86-13806087780 · [email protected]
上海岚克医药科技发展有限公司0086-21-58956006
Additional notes · 2 items

Definitionammonium carbonate: A colourlessor white crystalline solid,(NH4)2CO3, usually encountered asthe monohydrate. It is very soluble incold water. The compound decomposesslowly to give ammonia, water,and carbon dioxide. Commercial ‘ammoniumcarbonate’ is a double saltof ammonium hydrogencarbonateand ammonium aminomethanoate(carbamate), NH4HCO3.NH2COONH4.This material is manufactured byheating a mixture of ammoniumchloride and calcium carbonate andrecovering the product as a sublimedsolid. It readily releases ammoniaand is the basis of sal volatile. It isalso used in dyeing and wool preparationand in baking powders.

DefinitionA mixture of ammonium acid carbonate and ammo- nium carbamate.