Bisacetato[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphin]]ruthenium(II)
Basic information
- CAS
261948-85-0- Standard SMILES
CC(=O)O.CC(=O)O.[Ru].c1ccc(P(c2ccccc2)c2ccc3ccccc3c2-c2c(P(c3ccccc3)c3ccccc3)ccc3ccccc23)cc1- InChIKey
XANQJWCSQJDBEA-UHFFFAOYSA-N- Molecular formula
- C48H40O4P2Ru
- Average molar mass
- 843.8 g/mol
- Monoisotopic mass
- 844.144524
Names & identifiers
- Preferred name
- Bisacetato[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphin]]ruthenium(II)
- IUPAC
- acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium
- English name
- Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
- Molecular formula
- C48H40O4P2Ru
- Molecular weight
- 843.86
Names & synonyms
325146-81-4261948-85-0Bisacetato[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphin]]ruthenium(II)Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]Bisacetato((1S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphin))ruthenium(II)Diacetato((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)ruthenium(II) Ru(OAc)2((R)-binap)RefChem:569446689-262-0815-432-2(R)-Ru(OAc)2(BINAP)DIACETATO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II)(S)-Ru(OAc)2(BINAP)
Show more names
Ru-BINAPRu(OAc)2[(R)-binap]diacetoxyrutheniumDiacetato[(R-binaphthalene ≥(R)-Ru(OAc)?(BINAP)RU[(R)-BINAP](OCOH3)2Ru[(R)-BINAP](OCOCH3)2-binaphthyl]ruthenium(II)Diacetato[(R)-(+)-2,2'-bis(diphenyL
DIACETATO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II)Ru(BINAP)(OAc)2acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium(S)-Ru(OAc)2(BINAPDiacetato[(S)-()-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)SY010589F16636(R)-Ru(OAc)?(BINAP)
Properties
Computed structural properties
- Topological polar surface area
- 74.6 Ų
- Hydrogen bond donors
- 2
- Hydrogen bond acceptors
- 4
- Rotatable bonds
- 7
- Heavy atoms
- 55
- Formal charge
- 0
- Complexity
- 875
Physicochemical properties
- Melting point
- 100 °C · >100°C
- storage temp.
- 2 · 2-8°C
- form
- Powder
- color
- ocher to green
- Sensitive
- air sensitive
- InChIKey
- XANQJWCSQJDBEA-UHFFFAOYSA-N
- SMILES
- CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1
- UNSPSC Code
- 12352005 · 12352005
- NACRES
- 22 · NA.22
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319
- Precautionary statements
- 264 · P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
- WGK Germany
- 3 · 3
- HS Code
- 28439000 · 28439000
- Storage Class
- 11 · 11 - Combustible Solids
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H228 (50%): Flammable solid [Danger Flammable solids]
P210, P240, P241, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 2 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
Hazard information
Hazard Classes and CategoriesFlam. Sol. 2 (50%)
Safety data
- wgk
- 3
- hs_code
- 28439000
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- Storage Class
- 11 - Combustible Solids
- Hazard statements
- H315-H319
- Precautionary statements
- P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Chemistry & industry
Applications
Uses(R)-Ru(OAc)2(BINAP) is a catalyst.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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