Chloroiodomethane

HCID 11644CAS 593-71-5
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Basic information

Standard SMILES
ClCI
InChIKey
PJGJQVRXEUVAFT-UHFFFAOYSA-N
Molecular formula
CH2ClI
Average molar mass
176.38 g/mol
Monoisotopic mass
175.88897574

Overview

Chloroiodomethane is a halomethane.

Names & identifiers

Preferred name
Chloroiodomethane
IUPAC
chloro(iodo)methane
English name
Chloroiodomethane
Molecular formula
CH2ClI
Molecular weight
176.38

Names & synonyms

CHLOROIODOMETHANE593-71-5chloro(iodo)methaneMethane, chloroiodo-EINECS 209-804-8DTXSID50208034RefChem:575857DTXCID70130525209-804-8iodochloromethanechloro-iodomethaneMFCD00001078
Show more names
ICH2ClChloroiodomeoroiodomethaneChloroiodomethane 98%Chloroiodomethane,98%1-chloro-1-iodoMethaneChlorine Methyl iodide
X7AF9WG7CXChloroiodomethane; Chloromethyl iodideMethylene chloroiodideCH2ClIChloromethyl Iodide; IodochloromethaneChloromethyl iodideChloro-iodo-methanechloroiodo-methane

Database identifiers

CAS
593-71-5
PubChem CID
11644
DTXSID
DTXSID50208034
ChEBI
CHEBI:218584
UNII
X7AF9WG7CX
EC Number
209-804-8
Nikkaji
J457J

Properties

Computed structural properties

XLogP
1.6
Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
0
Heavy atoms
3

Experimental & physicochemical properties

Chemical ClassesOther Classes -> Halogenated Aliphatics, Saturated
SpringerMaterials PropertiesCoriolis coupling
Vapor Pressure10.6 [mmHg]
Physical DescriptionColorless or light brown liquid; [MSDSonline]

Physicochemical properties

Boiling point
108 · 108-109 °C (lit.)
Density
2.422 g/mL · 2.422 g/mL at 25 °C (lit.)
refractive index
20 · n20/D 1.582(lit.)
Flash point
108 · 108-109°C
storage temp.
Keep in dark place,Sealed in dry,Room Temperature
solubility
Miscible with acetone, benzene, diethyl ether and alcohol.

Safety & regulation

GHS classification

GHS Classification · 4 items

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 54 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory InformationChloroiodomethane: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryA skin and eye irritant; [eChemPortal: ERMA] An irritant; May be absorbed through skin; [MSDSonline]
Hazard Classes and CategoriesSkin Irrit. 2 (100%)

Safety data

F
8
PPE
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
wgk
3
ridadr
UN2810
hs_code
29034980
risk_code
36/37/38-20/21/22

Chemistry & industry

Applications · 3 items

DescriptionChloroiodomethane is a halogenated hydrocarbon that has been studied for its photolytic properties. For instance, the photolysis of chloroiodomethane in cryogenic matrices along with recombination of the nascent radical pair was studied.

UsesChloroiodomethane is used as an intermediate in pharmaceuticals, organic synthesis, agrochemicals and dyestuff. It is also useful in cyclopropanation (Simmon-Smith reaction), Mannich reaction, aminomethylation and in epoxidation.

General DescriptionThe photolysis of chloroiodomethane in cryogenic matrices along with recombination of the nascent radical pair was studied.

Upstream & downstream products

Suppliers50 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]

Related reactions

285 records
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Linked notes

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