CAS 4419-47-0 ethanamine, n-ethyl-, titanium(4+) salt (HCID 123216)

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Basic information

CAS: 4419-47-0
Standard SMILES: CC[N-]CC.CC[N-]CC.CC[N-]CC.CC[N-]CC.[Ti+4]
InChIKey: VJDVOZLYDLHLSM-UHFFFAOYSA-N
Molecular formula: C16H40N4Ti
Average molar mass: 336.38 g/mol
Monoisotopic mass: 336.273238

Names & identifiers

Preferred name: ethanamine, n-ethyl-, titanium(4+) salt
IUPAC: tetrakis(diethylazanide);titanium(4+)
English name: Tetrakis(diethylamino)titanium
Molecular formula: C16H40N4Ti
Molecular weight: 336.38

Names & synonyms

Tetrakis(diethylamino)titaniumEthanamine, N-ethyl-, titanium(4+) saltEthanamine, N-ethyl-, titanium(4+) salt (4:1)DTXSID0063446RefChem:591440DTXCID6040294437-500-74419-47-0Tetrakis(diethylamido)titanium(IV)diethylazanide;titanium(4+)Tetrakis(diethylamino)titanium(IV)Ti(NEt2)4

Show more names

TDEATamino)titanium(IV)titanium diethylamideTITANIUM (IV) DIETHYLAMIDETitanium isopropoxide(TDEAT)Tetrakis(diethylamion)titaniumTITANIUM TETRAKIS(DIETHYLAMIDE)Tertrakis（diethylamino）titaniumTETRAKIS (DIETHYLAMIDO) TITANIUM

MFCD00015648SCHEMBL42413Titanium, tetrakis(diethylamino)-DB-009830CS-0111541NS00125991H58035Tetrakis(diethylamido)titanium(IV), technical grade

Database identifiers

CAS: 4419-47-0
PubChem CID: 123216

Properties

Computed structural properties

Topological polar surface area: 4 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 4
Rotatable bonds: 8
Heavy atoms: 21
Formal charge: 0
Complexity: 74

Physicochemical properties

Melting point: 4 °C · 4 °C
Boiling point: 112 °C0.1 · 112 °C0.1 mm Hg(lit.)
Density: 0.931 g/mL · 0.931 g/mL at 25 °C(lit.)
refractive index: 20 · n20/D 1.536(lit.)
Flash point: -18 °F · -18 °F
storage temp.: 2 °C · Store at +2°C to +8°C.
solubility: Reacts with air.
form: liquid
color: yellow to orange
Specific Gravity: 0.95 · 0.95
Hydrolytic Sensitivity: 8 · 8: reacts rapidly with moisture, water, protic solvents
Sensitive: Moisture Sensitive
BRN: 3621431 · 3621431
InChI: 1S/4C4H10N.Ti/c4*1-3-5-4-2;/h4*3-4H2,1-2H3;/q4*-1;+4
InChIKey: VJDVOZLYDLHLSM-UHFFFAOYSA-N
SMILES: CCN(CC)[Ti](N(CC)CC)(N(CC)CC)N(CC)CC

Safety & regulation

GHS classification

GHS Classification · 5 items

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Hazard information

Regulatory Information · 3 items

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 10-11-2008 https://echa.europa.eu/registration-dossier/-/registered-dossier/9564

Tetrakis (diethylamino) titanium: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 2 (100%)；Skin Corr. 1B (100%)

Regulatory information

Regulatory Information · 3 items

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 10-11-2008 https://echa.europa.eu/registration-dossier/-/registered-dossier/9564

Tetrakis (diethylamino) titanium: Does not have an individual approval but may be used under an appropriate group standard

Safety data

F: 10-21
PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk: 3
tsca: TSCA listed

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationEthanamine, N-ethyl-, titanium(4+) salt (4:1): ACTIVE

Applications · 3 items

DescriptionTetrakis (diethylamino) titanium is useful Ti-source precusor. Tetrakis (diethylamino) titanium is useful in TiN film deposition using the atomic layer deposition method1,2. It is also a useful compound during the process of etching a layer of diamond like carbon.

UsesPrecursors Packaged for Depositions Systems

General DescriptionAtomic number of base material: 22 Titanium