Stannane, 1,1'-thieno[3,2-b]thiophene-2,5-diylbis[1,1,1-trimethyl-
Basic information
- CAS
469912-82-1- Standard SMILES
[CH3][Sn]([CH3])([CH3])[c]1cc2s[c]([Sn]([CH3])([CH3])[CH3])cc2s1- InChIKey
HDZULVYGCRXVNQ-UHFFFAOYSA-N- Molecular formula
- C12H20S2Sn2
- Average molar mass
- 465.8 g/mol
- Monoisotopic mass
- 467.90505
Names & identifiers
- Preferred name
- Stannane, 1,1'-thieno[3,2-b]thiophene-2,5-diylbis[1,1,1-trimethyl-
- IUPAC
- trimethyl-(5-trimethylstannylthieno[3,2-b]thiophen-2-yl)stannane
- English name
- 2,5‐ bis(triMethylstannyl)th ieno[3,2‐b]thiophene
- Molecular formula
- C12H20S2Sn2
- Molecular weight
- 465.84
Names & synonyms
469912-82-1Stannane, 1,1'-thieno(3,2-b)thiophene-2,5-diylbis(1,1,1-trimethyl-Stannane, 1,1'-thieno[3,2-b]thiophene-2,5-diylbis[1,1,1-trimethyl-RefChem:888921807-949-72,5-bis(trimethylstannyl)thieno[3,2-b]thiophene2,5-Bis(trimethylstannyl)-thieno[3,2-b]thiophenetrimethyl-(5-trimethylstannylthieno[3,2-b]thiophen-2-yl)stannaneStannane, thieno[3,2-b]thiophene-2,5-diylbis[trimethyl-SCHEMBL12789272,5(c)\ bis(triMethylstannyl)th ieno[3,2(c)\b]thiopheneHDZULVYGCRXVNQ-UHFFFAOYSA-N
Show more names
TT-2SnBTH-2Sn5‐bis(triMethylstannyl)thieno[32,5-Bis(trimethylstannyl)thieno[3,2-b]thioph2,5-Bis(trimethylsilyl)thieno[3,2-b]thiophene2,5‐ bis(triMethylstannyl)th ieno[3,2‐b]thiophene2,5-Bis(trimethylstannyl)thieno[3,2-b]thiophene>Silane, thieno[3,2-b]thiophene-2,5-diylbis[trimethyl-
AKOS025401937CS-W018456AC-27448DA-27244B4536F205622,5-bis-trimethylstannyl-thieno[3,2-b]thiophene2,5-Bis-trimethylstannylthieno[3,2-b]thiophene
Database identifiers
- CAS
469912-82-1- PubChem CID
- 12978043
- EC Number
- 807-949-7
- Nikkaji
- J1.638.010E
Properties
Computed structural properties
- Topological polar surface area
- 56.5 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 2
- Heavy atoms
- 16
- Formal charge
- 0
- Complexity
- 239
Physicochemical properties
- Melting point
- 127 · 127-132 °C
- Boiling point
- 383.8 · 383.8±52.0 °C(Predicted)
- storage temp.
- -20 °C · Storage temp. -20°C
- form
- powder to crystal
- color
- White to Amber to Dark green
- InChI
- InChI=1S/C6H2S2.6CH3.2Sn/c1-3-7-6-2-4-8-5(1)6;;;;;;;;/h1-2H;6*1H3;;
- InChIKey
- HDZULVYGCRXVNQ-UHFFFAOYSA-N
- SMILES
- C12C=C([Sn](C)(C)C)SC=1C=C([Sn](C)(C)C)S2
- UNSPSC Code
- 12352103 · 12352103
- NACRES
- 23 · NA.23
- Symbol(GHS)
- 6 · GHS06,GHS09
- Signal word
- Danger
- Hazard statements
- 300 · H300+H310+H330-H410
- Precautionary statements
- 260 · P260-P262-P273-P280-P302+P352+P310-P304+P340+P310
- Hazard Codes
- T+,N
- Risk Statements
- 26 · 26/27/28-50/53
- Safety Statements
- 26 · 26-27-28-45-60-61
- RIDADR
- 3146 · UN 3146 6.1/PG I
- WGK Germany
- 3 · WGK 3
- HS Code
- 2934.99 · 2934.99.4400
- HazardClass
- 6.1 · 6.1
- PackingGroup
- I
- Storage Class
- 6.1 A · 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
- Hazard Classifications
- 1 DermalAcute · Acute Tox. 1 DermalAcute Tox. 2 InhalationAcute Tox. 2 OralAquatic Acute 1Aquatic Chronic 1
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H300+H310+H330 (100%): Fatal if swallowed, in contact with skin or if inhaled [Danger Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]
P260, P262, P264, P270, P271, P273, P280, P284, P301+P316, P302+P352, P304+P340, P316, P320, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 3 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesAcute Tox. 2 (100%)
Safety data
- wgk
- WGK 3
- ridadr
- UN 3146 6.1/PG I
- hs_code
- 2934.99.4400
- risk_code
- 26/27/28-50/53
- Signal word
- Danger
- Symbol(GHS)
- GHS06,GHS09
- hazard_code
- T+,N
- safety_code
- 26-27-28-45-60-61
- hazard_class
- 6.1
- Storage Class
- 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
- packing_group
- I
- Hazard statements
- H300+H310+H330-H410
- Hazard Classifications
- Acute Tox. 1 DermalAcute Tox. 2 InhalationAcute Tox. 2 OralAquatic Acute 1Aquatic Chronic 1
- Precautionary statements
- P260-P262-P273-P280-P302+P352+P310-P304+P340+P310
Chemistry & industry
Applications
Description2,5-bis(trimethylstannyl)thieno[3,2-b]thiophene can be prepared by using thieno[3,2-b]thiopheneas starting material, further reaction with dibromo compounds (Stille Coupling) to form oligomers or polymers which can be used for organic electronic devices.
Uses2,5-Bis(trimethylstannyl)-thieno[3,2-b]thiophene can be used as a copolymer in the synthesis of thiophene based materials for the fabrication of organic electronic devices such as organic field effect transistors (OFETs), organic thin film transistors(OTFTs) and organic photovoltaic cells (OPVs).
General Description2,5-Bis(trimethylstannyl)-thieno[3,2-b]thiophene is a conducting polymer that can be used in the formation of the hole transporting material (HTM) with improved charge mobility. It is a majorly utilized as a copolymer in the polymerization of new thieno(3,2-b)thiophene based polymers.
Upstream & downstream products
Upstream raw materials
Related reactions
4 records
Compound notes
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