Basic information
- CAS
815-82-7- Standard SMILES
O=C([O-])[C@H](O)[C@@H](O)C(=O)[O-].[Cu+2]- InChIKey
RSJOBNMOMQFPKQ-ZVGUSBNCSA-L- Molecular formula
- C4H4CuO6
- Average molar mass
- 211.62 g/mol
- Monoisotopic mass
- 210.930385
Overview
Cupric tartrate appears as a green to blue odorless powder. Insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is noncombustible. Used for electroplating metals.
Names & identifiers
- Preferred name
- Cupric tartrate
- IUPAC
- copper (2R,3R)-2,3-dihydroxybutanedioate
- English name
- Cupric tartrate
- Molecular formula
- C4H6CuO6
- Molecular weight
- 213.63
Names & synonyms
815-82-7CUPRIC TARTRATEcopper(II) tartrateUNII-GQ7IFQ18IRGQ7IFQ18IRHSDB 2692,3-Dihydroxybutanedioic acid copper saltEINECS 212-425-0NSC 112251CUPRIC TARTRATE [MI]CUPRIC TARTRATE [HSDB]DTXSID00883592
Show more names
COPPER(II) TARTRATE HYDRATENA-9111(±)-Tartaric acidKupfer(II)-tartratCUPRIC TARTRATE HYDRATECopper(II) (+)-L-tartrateCOPPER TARTRATE TRIHYDRATECUPRIC TARTRATE TRIHYDRATE
Tartaric acid, copper(2+) salt (1:1), (+)-NSC-112251(2R,3R)-2,3-Dihydroxybutanedioic acid copper (2+) salt (1:1)Butanedioic acid, 2,3-dihydroxy-, (R-(R*,R*))-, copper(2+) salt (1:1)BUTANEDIOIC ACID, 2,3-DIHYDROXY-(R-(R*,R*))-, COPPER(2+) SALT (1:1)BUTANEDIOIC ACID, 2,3-DIHYDROXY-[R-(R*,R*)]-, COPPER(2+) SALT (1:1)RefChem:128842DTXCID601023106
Database identifiers
- CAS
815-82-7- PubChem CID
- 13155
- DTXSID
DTXSID00883592
Properties
Computed structural properties
- Topological polar surface area
- 121 Ų
- Hydrogen bond donors
- 2
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 1
- Heavy atoms
- 11
- Formal charge
- 0
- Complexity
- 123
Experimental & physicochemical properties
Chemical ClassesMetals -> Metals, Inorganic Compounds
Densitygreater than 1 (USCG, 1999)
Color/FormLIGHT BLUE POWDER
SolubilityGreen to blue, odorless powder; slightly sol in water; sol in acids, alkali solns. /Trihydrate/
Boiling PointTrihydrate decomposes on heating (USCG, 1999)
Physical Description
Cupric tartrate appears as a green to blue odorless powder. Insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is noncombustible. Used for electroplating metals.
Light blue powder; [HSDB] Blue-green odorless crystalline powder; [MSDSonline]
Physicochemical properties
- Melting point
- 275 °C · ~275 °C (dec.)(lit.)
- storage temp.
- 2 · under inert gas (nitrogen or Argon) at 2-8°C
- solubility
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Warning
H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]
P264, P270, P301+P317, P330, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory.
Hazard information
Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
Health Hazards
INHALATION: Inhalation of dust may cause nasal congestion. EYES: May cause conjunctivitis and edema of eyelids. SKIN: May irritate skin. INGESTION: Vomiting is caused by local irritant and astringent action of ionic copper on stomach and bowel. (USCG, 1999)
Hazards SummaryCan cause copper poisoning after ingestion; [HSDB] An irritant; May cause liver and kidney damage; [MSDSonline] See Copper.
Reactive GroupAlcohols and Polyols
OSHA StandardsPermissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 1 mg/cu m. /Copper dusts and mists (as Cu)/
Reactivity Profile
Acidic salts, such as CUPRIC TARTRATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Chemistry & industry
Uses & manufacturing
Uses
Used in baths for copper electroplating; [Merck Index]
Electroplating [Category: Plate]
In baths for copper electroplating
Methods of ManufacturingPrepd by reaction of K tartrate with Cu(NO3)2: Kirschner, Kiesling, J. Am. Chem. Soc. 82, 4174 (1960).
General Manufacturing InformationButanedioic acid, 2,3-dihydroxy- (2R,3R)-, copper(2+) salt (1:1): ACTIVE
Applications
UsesCopper(II) Tartrate can be useful in gas-induced formation of Cu nanoparticle as catalyst for high-purity straight and helical carbon nanofibers.
General DescriptionA green to blue odorless powder. Insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Cupric tartrate is noncombustible. Used for electroplating metals.
Suppliers53 total
北京华美互利生物化工010-56205725 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]
江苏星科元信息科技有限公司400-605-7200 15335295587 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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