n-Propyl acrylate
Basic information
- CAS
24979-82-6- Standard SMILES
C=CC(=O)OCCC- InChIKey
PNXMTCDJUBJHQJ-UHFFFAOYSA-N- Molecular formula
- C6H10O2
- Average molar mass
- 114.14 g/mol
- Monoisotopic mass
- 114.06807956
Overview
N-Propyl acrylate is an acrylate ester.
Names & identifiers
- Preferred name
- n-Propyl acrylate
- IUPAC
- propyl prop-2-enoate
- English name
- Poly(n-propyl acrylate)
- Molecular formula
- C6H10O2
- Molecular weight
- 114.1424
Names & synonyms
n-Propyl acrylate925-60-0Propyl acrylatepropyl prop-2-enoate2-PROPENOIC ACID, PROPYL ESTERPropyl 2-propenoateAcrylic acid, propyl esterAllyln-propylether24979-82-6MFCD00048693NSC-32620T23G14902U
Show more names
25%soln.intoluenePoly(propyl acrylate)Poly(n-propyl acrylate)N-PROPYL ACRYLATE POLYMERPoly(propyl 2-propenoate)PolynpropylacrylateintoluenePoly[1-(propoxycarbonyl)ethylene]Poly(n-propyl acrylate)(25% in toluene)2-Propenoic acid, propyl ester, homopolymer
1-Propyl acrylatePropylacrylateCCRIS 8584UNII-T23G14902UHSDB 5443EINECS 213-120-5NSC 32620Acrylic acid n-propyl ester
Database identifiers
- CAS
24979-82-6、925-60-0- PubChem CID
- 13550
- DTXSID
DTXSID6061288- ChEBI
CHEBI:229305- UNII
- T23G14902U
- EC Number
- 213-120-5
- Nikkaji
- J82.108J
Properties
Computed structural properties
- XLogP
- 2
- Topological polar surface area
- 26.3 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 4
- Heavy atoms
- 8
- Formal charge
- 0
- Complexity
- 86.5
Experimental & physicochemical properties
Chemical ClassesOther Classes -> Esters, Other
SpringerMaterials PropertiesBoiling point
Boiling Point
122 °C
BP: 63 °C at 100 mm Hg
Vapor Pressure14.5 [mmHg]
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical DescriptionColorless liquid; [MSDSonline]
Physicochemical properties
- Flash point
- 40 · 40
- form
- Solution in toluene (Unit weight does not include weight of solvent.)
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Warning
H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P273, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 5 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazards SummaryEmergency treatment: Irritants; Acrylic acid esters of lower molecular weight cause skin, eye, and mucous membrane irritation; Inhalation may be very toxic; [HSDB] A severe eye irritant; [MSDSonline]
Safety & protection
Disposal Methods
SRP: Criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
Preventive MeasuresAdequate exhaust ventilation should be provided to protect the worker from inhalation of fumes. Maintenance and good housekeeping should be ensured. /Acrylic resins/
Personal Protective Equipment (PPE)Workers should be provided with hand protection and eye and face protection. /Acrylic resins/
Toxicology
Human Toxicity Excerpts
/SIGNS AND SYMPTOMS/ The lower-molecular-wt esters of acrylic acids are irritants to skin, eyes, and mucous membranes. /Esters of acrylic acid/
/SIGNS AND SYMPTOMS/ Inhalation ... can lead to serious toxic events... /Esters of acrylic acid/
Antidote and Emergency Treatment
/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Esters and related compounds/
/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Provide a low-stimulus environment. Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Treat frostbite by rapid rewarming ... . /Esters and related compounds/
/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Esters and related compounds/
Chemistry & industry
Uses & manufacturing
Uses
Used as a monomer; No known current manufacture in the US; [HSDB]
Monomer
U.S. Exports
(1979) No data
(1981) No data
U.S. Imports
(1979) No data
(1981) No data
U.S. Production
(1979) No evidence of commercial production in U.S.
(1981) No evidence of commercial production in U.S.
Consumption Patterns
45% for coatings, 16% for textiles & leather finishes, 9% for paper coatings, 8% for adhesives, 6% for polyacrylates, 5% for polishes, 5% for acrylic fibers, 6% other (1983 est) /Acrylates and acrylic acid/
(All acrylic acid esters) 46% as a monomer for emulsion polymers and solution polymers in latex paints; 26% as a monomer for emulsion polymers in textile applications; 6% as a comonomer for acrylic fibers; 6% as a monomer for emulsion polymers in polishes; 6% as a monomer for emulsion polymers in paper applications; 4% as a monomer for emulsion polymers used in base coatings and surface impregnation of natural leather; 6% in misc applications (1973)
Methods of ManufacturingTransesterification or esterification of N-propyl alcohol with either methyl acrylate or acrylic acid
General Manufacturing Information
2-Propenoic acid, propyl ester: ACTIVE
Alkyl mercury compounds have been used as seed disinfectants and for fungicides. They have also been used in organic synthesis. /Mercury alkyl compounds/
Related reactions
1 records
Compound notes
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