Basic information
- CAS
1636-14-2- Standard SMILES
CCN(CC)P(c1ccccc1)N(CC)CC- InChIKey
HTIVDCMRYKVNJC-UHFFFAOYSA-N- Molecular formula
- C14H25N2P
- Average molar mass
- 252.34 g/mol
- Monoisotopic mass
- 252.1755358
Names & identifiers
- Preferred name
- Phenylbis(diethylamino)phosphine
- IUPAC
- N-[diethylamino(phenyl)phosphanyl]-N-ethylethanamine
- English name
- BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97
- Molecular formula
- C14H25N2P
- Molecular weight
- 252.34
Names & synonyms
1636-14-2Phenylbis(diethylamino)phosphineNSC 244337DTXSID00167622RefChem:369836DTXCID1090113Bis(diethylamino)phenylphosphineN-[diethylamino(phenyl)phosphanyl]-N-ethylethanamineBIS(DIETHYLAMINO)PHENYLPHOSPHINE 97NSC244337[(DIETHYLAMINO)(PHENYL)PHOSPHANYL]DIETHYLAMINESCHEMBL2226790
Show more names
Phenylphosphonous tetraethyldiamideBis(diethylamino)phenylphosphine 97%BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97N,N,N′N′-Tetraethylphenylphosphonous diamiden,n,n',n'-Tetraethyl-1-phenylphosphanediaminePhosphonous diamide, N,N,N',N'-tetraethyl-P-phenyl-
tetraethylphenylphosphonous diamideBis(diethylamino)phenylphosphine, 97%NSC-244337N,N,N',N'-Tetraethyl-P-phenylphosphonous diamide
Database identifiers
- CAS
1636-14-2- PubChem CID
- 137129
- DTXSID
DTXSID00167622- Nikkaji
- J1.073.990J
Properties
Computed structural properties
- XLogP
- 3.4
- Topological polar surface area
- 6.5 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 7
- Heavy atoms
- 17
- Formal charge
- 0
- Complexity
- 173
Physicochemical properties
- Boiling point
- 80 °C0.005 · 80 °C0.005 mm Hg(lit.)
- Density
- 0.971 g/mL · 0.971 g/mL at 25 °C(lit.)
- Flash point
- 223 °F · 223 °F
- pka
- 6.94 · 6.94±0.70(Predicted)
- form
- liquid
- InChI
- 1S/C14H25N2P/c1-5-15(6-2)17(16(7-3)8-4)14-12-10-9-11-13-14/h9-13H,5-8H2,1-4H3
- InChIKey
- HTIVDCMRYKVNJC-UHFFFAOYSA-N
- SMILES
- CCN(CC)P(N(CC)CC)c1ccccc1
- UNSPSC Code
- 12352002 · 12352002
- PPE
- Eyeshields, Gloves
- WGK Germany
- 3 · 3
- Storage Class
- 10 · 10 - Combustible liquids
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
Safety data
- PPE
- Eyeshields, Gloves
- wgk
- 3
- Storage Class
- 10 - Combustible liquids
Chemistry & industry
Applications
UsesElectron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions. Ligand precatalyst for Heck coupling reactions. Reactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions. Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling. Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites.
UsesElectron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactionsLigand precatalyst for Heck coupling reactionsReactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactionsPreparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura couplingTrimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites
Suppliers17 total
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
广东方信生物科技有限公司0751-2838688 13376594225 · [email protected]
济南大宇化工有限公司531-87153728 13805401165 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
武汉峰耀同辉化学制品有限公司027-87466205 15377579727 · [email protected]
广东翁江化学试剂有限公司0751-2886766 13927870850 · [email protected]
成都标样生物科技有限公司028-81700200 13308200041 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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