Triphenylarsine oxide

HCID 14382

Basic information

CAS
1153-05-5
Standard SMILES
O=[As](c1ccccc1)(c1ccccc1)c1ccccc1
InChIKey
CLVJBRYGLQNRDA-UHFFFAOYSA-N
Molecular formula
C18H15AsO
Average molar mass
322.2 g/mol
Monoisotopic mass
322.033885

Names & identifiers

Preferred name
Triphenylarsine oxide
IUPAC
diphenylarsorylbenzene
English name
Triphenylarsine oxide
Molecular formula
C18H15AsO
Molecular weight
322.23

Names & synonyms

TRIPHENYLARSINE OXIDEArsine oxide, triphenyl-EINECS 214-571-0NSC 12673DTXSID1061570Arsine oxide, triphenylRefChem:191899DTXCID2033364UN3465214-571-01153-05-5diphenylarsorylbenzene
Show more names
(C6H5)3As=OTriphenyloxoarsorane
(diphenylarsoroso)benzeneTriphenylarsenic oxidetriphenyl arsinoxideTriphenyl-arsineoxidTriphenylarsaniumolateTPAOtriphenyl arsine oxideTriphenylarsine oxide, 97%

Database identifiers

CAS
1153-05-5
PubChem CID
14382
DTXSID
DTXSID1061570
EC Number
214-571-0
Nikkaji
J203.407G

Properties

Computed structural properties

Topological polar surface area
17.1 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
1
Rotatable bonds
3
Heavy atoms
20

Experimental & physicochemical properties

Physical DescriptionFaintly beige crystals; [Aldrich MSDS] Insoluble in water; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
191 · 191-193 °C (lit.)
Boiling point
468.4 · 468.4±28.0 °C(Predicted)
storage temp.
Poison room
form
powder
BRN
2939833 · 2939833
InChI
1S/C18H15AsO/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

Safety & regulation

GHS classification

GHS Classification · 5 items

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral];H331 (100%): Toxic if inhaled [Danger Acute toxicity, inhalation];H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Regulatory InformationRestricted substance: Triphenylarsine oxide;EC: 214-571-0;Restriction condition document: PDF link
Hazards Summary · 1 item

Almost nothing is known regarding health effects of organic arsenic compounds in humans. Studies in animals show that some simple organic arsenic compounds are less toxic than inorganic forms. Ingestion of methyl and dimethyl compounds can cause diarrhea and damage to the kidneys. [ATSDR ToxProfiles] An irritant; Toxic by ingestion, inhalation, and skin absorption; Limited evidence of carcinogenicity; [Aldrich MSDS] See Dimethylarsenic acid.

Hazard Classes and CategoriesAcute Tox. 3 (100%);Acute Tox. 3 (100%);Aquatic Acute 1 (100%);Aquatic Chronic 1 (100%)

Safety & protection

Permissible Exposure Limit (PEL)0.5 [mg/m3], as As

Regulatory information

Regulatory InformationRestricted substance: Triphenylarsine oxide;EC: 214-571-0;Restriction condition document: PDF link

Safety data

PPE
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
wgk
3
tsca
TSCA listed
ridadr
UN 3465 6.1/PG 2
hs_code
29310099
risk_code
23/25-50/53

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationArsine oxide, triphenyl-: ACTIVE

Suppliers11 total

Aladdin Scientific[email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
青岛海智微元生物科技有限公司18317699790 18317699790 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]

Related reactions

2 records

Compound notes

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