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Methylmercury hydroxide

HCID 14451
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationRelated reactionsCompound notes
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Basic information

CAS
1184-57-2
Standard SMILES
[CH3][Hg+].[OH-]
InChIKey
KRZWEBVPFGCYMY-UHFFFAOYSA-M
Molecular formula
CH3HgOH
Average molar mass
232.63 g/mol
Monoisotopic mass
233.996858

Overview

Greenish-white powder or flakes with an unpleasant odor. (NTP, 1992)

Names & identifiers

Preferred name
Methylmercury hydroxide
IUPAC
methylmercury(1+) hydroxide

Names & synonyms

Hydroxymethylmercury1184-57-2Methylmercuric hydroxideMETHYLMERCURY HYDROXIDEMethylhydroxymercuryPanogen Soil DrenchMercury, hydroxymethyl-Methyl mercury hydroxideEZ74BDI0HBDTXSID3025621NSC-19997CH(3)HgOH
Show more names
RefChem:158264DTXCID705621214-667-2Methylmercury(II) hydroxidemethylmercury(1+);hydroxideHydroxymethyl mercuryCaswell No. 573Dmethylmercury(1+) hydroxide

Database identifiers

CAS
1184-57-2
PubChem CID
14451
DTXSID
DTXSID3025621
UNII
EZ74BDI0HB
EC Number
214-667-2

Properties

Computed structural properties

Topological polar surface area
1 Ų
Hydrogen bond donors
1
Hydrogen bond acceptors
1
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
2

Experimental & physicochemical properties

Solubility1 to 10 mg/mL at 70 °F (NTP, 1992)
Melting Point279 °F (NTP, 1992)
Physical DescriptionGreenish-white powder or flakes with an unpleasant odor. (NTP, 1992)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H300 (100%): Fatal if swallowed [Danger Acute toxicity, oral]

P260, P262, P264, P270, P271, P273, P280, P284, P301+P316, P302+P352, P304+P340, P316, P319, P320, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 4 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

DOT LabelPoison
Fire HazardsFlash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
Health Hazards · 1 item

SYMPTOMS: Symptoms associated with compounds of this class may occur weeks to months after an acute exposure to toxic concentrations. Acute and chronic symptoms are similar and include numbness and tingling of the lips, hands and feet; dysarthria, concentric constriction of the visual fields, hearing impairment and ataxia. Clumsiness, speech impairment, slight ptosis, irregular nystagmus on extremes of gaze, "jerky pursuit" and abnormal saccadic movements are common. It can cause chorea, athetosis, tremor and convulsions. Other symptoms may include irritation of the eyes, skin and mucous membranes, and emotional disturbances. Severe intoxication can produce periods of spasticity and jerking movements of the limbs, head or shoulders; bouts of groaning, moaning, shouting or crying; and incontinence. Less frequent symptoms include dizziness, hypersalivation, lacrimation, nausea, vomiting, diarrhea, constipation, kidney damage, dermatitis and skin burns. Damage tends to be irreversible. This type of compound passes through the blood brain barrier and placenta very rapidly.

Reactive GroupSalts, Basic

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationRelated reactionsCompound notes
Reactivity Profile
METHYL MERCURY HYDROXIDE is incompatible with oxidizing materials, acid and acid fumes. (NTP, 1992)
Air and Water ReactionsThis chemical is sensitive to air and light. Slightly soluble in water.

Safety & protection

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 item

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 item

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.
Immediately Dangerous to Life or Health (IDLH)2 mg Hg/m3 (NIOSH, 2024)