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Dioxogermane

HCID 14796
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Basic information

CAS
1310-53-8
Standard SMILES
[O]=[Ge]=[O]
InChIKey
YBMRDBCBODYGJE-UHFFFAOYSA-N
Molecular formula
GeO2
Average molar mass
104.63 g/mol
Monoisotopic mass
105.911007

Names & identifiers

Preferred name
Dioxogermane
IUPAC
dioxogermane
English name
Germanium oxide
Molecular formula
GeO2
Molecular weight
104.64

Names & synonyms

1310-53-8dioxogermaneGermanic acidGeO2DioxogermaniumGermanic oxideGermanium tetroxideWLN: GE O2MFCD00011030Germanium Oxide Nanoparticle DispersionSCHEMBL105462Germanium(IV) oxide 99.999%
Show more names
GERMANIUM DIOXIDEGERMANIUM(IV) OXIDEGermaniumdioxidGermaniagermanicacidGERMANIUM OXIDE
NSC294212AKOS015904129FG76402GERMANIUM DIOXIDE, 99.999%Germanium(IV) oxide (hexagonal, quartz type) GECS-0196667NS00076163F20443

Database identifiers

CAS
1310-53-8
PubChem CID
14796
Nikkaji
J3.631.938K

Properties

Computed structural properties

Topological polar surface area
34.1 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
18.3

Experimental & physicochemical properties

Physical DescriptionDry Powder

Physicochemical properties

Melting point
400 °C · >400 °C(lit.)
Density
6.239 g/mL · 6.239 g/mL at 25 °C
bulk density
1430 kg/m3 · 1430kg/m3
vapor pressure
0 Pa · 0Pa at 25℃
refractive index
1.99 · 1.99
storage temp.
no restrictions.
solubility
ethylene glycol: soluble
form
Powder/Flake/Crystalline/Beads/Lump, Etc.
Specific Gravity
6.239 · 6.239
color
White
Water Solubility
0.4 g/100 · 0.4 g/100 mL
Specific Heat Capacity
0.5 J/ · Cp(crystal): 0.5 J/(g·K), at 25℃
Crystal Structure
Quartz type

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Hazard information

Regulatory Information · 3 items

Chemical: Germanium oxide (GeO2)

Germanium oxide (GeO2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Germanium oxide (GeO2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Germanium oxide (GeO2): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Safety data

PPE
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
wgk
1
tsca
TSCA listed
rtecs
LY5240000
hs_code
2825 60 00
Toxicity
LD50 i.p. in rats: 750 mg/kg, Rosenfeld, Wallace, Arch. Ind. Hyg. Occup. Med. 8, 466 (1953)
risk_code
22
Signal word
Warning
Symbol(GHS)
GHS07
hazard_code
Xn
safety_code
22-24/25
Storage Class
11 - Combustible Solids
Hazard statements
H302
REACH Registrations
Active
Hazard Classifications
Acute Tox. 4 Oral
Precautionary statements
P264-P270-P301+P312-P501
Hazardous Substances Data
1310-53-8(Hazardous Substances Data)

Chemistry & industry

Uses & manufacturing

U.S. Production2023: 43,676 lb
Consumer UsesCatalyst
Industry UsesCatalyst
General Manufacturing Information · 2 items

All Other Basic Inorganic Chemical Manufacturing

Germanium oxide (GeO2): ACTIVE

Applications · 5 items

UsesGermanium oxide has high refractive index and infrared transmission, for which it is used in industrial glasses. It also is used in preparation of high purity grade germanium.

DescriptionGermanium oxide also called Germanium dioxide is the oxide of germanium, an inorganic compound, featuring the chemical formula GeO2. It is formed as a passivation layer on pure germanium after exposure to oxygen. Germanium dioxide generally has a low toxicity, but shows severe nephrotoxicity at higher doses. Germanium dioxide is still offered on the market in some questionable miracle therapies. Exposure to high doses of germanium dioxide can lead to germanium poisoning.

UsesGermanium dioxide is used as an optical material for wide-angle lenses and in optical microscope objective lenses. It is used as a catalyst in the preparation of polyethylene terephthalate resin. Further, it is used as a feedstock for the manufacturing of phosphors and semiconductor materials. It is also used in transistors and diodes, and infrared transmitting glass.

UsesGermanium oxide can be used in Phosphors, transistors and diodes, infraredtransmitting glass.

UsesWhen Germanium dioxide is 99.999% pure, it is used as a semiconductor in transistors, in diodes, and to make special infrared transmitting glass.

Preparation methods · 1 item

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Related reactions

2 records
New reaction record
HRID 1085621 reaction equation
HRID 1085621As reactantuspto-grants-1991_04
HRID 2250541 reaction equation
HRID 2250541As catalystuspto-grants-2008_01

Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
crystal system
Three sides
Merck
14 · 14,4409
Solubility Product Constant (Ksp)
57 · pKsp: 57
Space group
3221 · P3221
Lattice constant
a/nm
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
302 · H302
Precautionary statements
264 · P264-P270-P301+P312-P501
PPE
95 · dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes
Xn
Risk Statements
22 · 22
Safety Statements
22 · 22-24/25
WGK Germany
1 · 1
RTECS
5240000 · LY5240000
TSCA
TSCA listed
HS Code
2825 · 2825 60 00
Storage Class
11 · 11 - Combustible Solids
Hazard Classifications
4 Oral · Acute Tox. 4 Oral
Hazardous Substances Data
1310 · 1310-53-8(Hazardous Substances Data)
Toxicity
50 i.p · LD50 i.p. in rats: 750 mg/kg, Rosenfeld, Wallace, Arch. Ind. Hyg. Occup. Med. 8, 466 (1953)
REACH Registrations
Active

PreparationGermanium oxide is prepared by heating germanium with oxygen at elevated temperatures, or by hydrolysis of germanium(IV) halides:GeCl4 + 2H2O → GeO2 + 4HClIt also is prepared by oxidation of germanium(II) sulfide:GeS + 2O2 GeO2 + SO2The product obtained in the above reactions is in the form of hexagonal modification of GeO2.

Upstream & downstream products

Upstream raw materials

GERMANIUM(IV) CHLORIDE

Downstream products

GERMANIUM(IV) CHLORIDE