Basic information
- CAS
1317-39-1- Standard SMILES
O.[Cu].[Cu]- InChIKey
LBJNMUFDOHXDFG-UHFFFAOYSA-N- Molecular formula
- Cu2H2O
- Average molar mass
- 145.11 g/mol
- Monoisotopic mass
- 143.869759
Names & identifiers
- Preferred name
- Dicopper oxide
- IUPAC
- copper;hydrate
- English name
- Cuprous oxide
- Molecular formula
- Cu2O
- Molecular weight
- 143.09
Names & synonyms
Show more names
Database identifiers
- CAS
1317-39-1- PubChem CID
- 14830
- UNII
- T8BEA5064F
- Nikkaji
- J95.201J
Properties
Computed structural properties
- Topological polar surface area
- 1 Ų
- Hydrogen bond donors
- 1
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 0
- Heavy atoms
- 3
- Formal charge
- 0
- Complexity
- 2
Physicochemical properties
- Melting point
- 1232 °C · 1232 °C
- Boiling point
- 1800 °C · 1800 °C
- Density
- 6 g/mL · 6 g/mL at 25 °C (lit.)
- refractive index
- 2.705 · 2.705
- Flash point
- 1800 °C · 1800°C
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- 2 O · insoluble in H2O
- form
- powder
- color
- red
- Specific Gravity
- 6 · 6.
- Water Solubility
- practically insoluble
- Specific Heat Capacity
- 0.44 J/ · Cp(crystal): 0.44 J/(g·K), at 25℃
- Crystal Structure
- 2 O · Cu2O type
- Sensitive
- Air & Moisture Sensitive
- Merck
- 14 · 14,2664
- crystal system
- Cube
- Space group
- 3 m · Pn3m
- Lattice constant
- a/nm
- Symbol(GHS)
- 2 · GHS02,GHS07,GHS09
- Signal word
- Danger
- Hazard statements
- 225 · H225-H319-H410
- Precautionary statements
- 210 · P210-P233-P240-P241-P273-P305+P351+P338
- PPE
- 95 · dust mask type N95 (US), Eyeshields, Faceshields, Gloves
- Hazard Codes
- Xn,N,F
- Risk Statements
- 22 · 22-50/53-51/53-11
- Safety Statements
- 22 · 22-60-61-16-7
- RIDADR
- 3077 · UN 3077 9/PG 3
- WGK Germany
- 3 · 3
- RTECS
- 8050000 · GL8050000
- TSCA
- TSCA listed
- HazardClass
- 9 · 9
- PackingGroup
- III
- HS Code
- 28255000 · 28255000
- Storage Class
- 11 · 11 - Combustible Solids
- Hazard Classifications
- 4 InhalationAcute · Acute Tox. 4 InhalationAcute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Eye Dam. 1
- Hazardous Substances Data
- 1317 · 1317-39-1(Hazardous Substances Data)
- Toxicity
- 50 orally · LD50 orally in rats: 0.47 g/kg (Smyth)
- REACH Registrations
- Active
- Limited Quantities
- 5 kg · 5.0 kg (11 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Safety & regulation
Safety data
- PPE
- dust mask type N95 (US), Eyeshields, Faceshields, Gloves
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- GL8050000
- ridadr
- UN 3077 9/PG 3
- hs_code
- 28255000
- Toxicity
- LD50 orally in rats: 0.47 g/kg (Smyth)
- risk_code
- 22-50/53-51/53-11
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS07,GHS09
- hazard_code
- Xn,N,F
- safety_code
- 22-60-61-16-7
- hazard_class
- 9
- Storage Class
- 11 - Combustible Solids
- packing_group
- III
- Hazard statements
- H225-H319-H410
- Limited Quantities
- 5.0 kg (11 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
- REACH Registrations
- Active
- Hazard Classifications
- Acute Tox. 4 InhalationAcute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Eye Dam. 1
- Precautionary statements
- P210-P233-P240-P241-P273-P305+P351+P338
- Hazardous Substances Data
- 1317-39-1(Hazardous Substances Data)
Chemistry & industry
Applications
Uses1. It can be used for coating of ship bottom coating, pesticide germicide, and glaze and used for copper oxide rectifier, photocell, electroplating and copper salt production. 2. It can be used in the manufacture of antifouling paint (used to kill low-level marine animals), pesticides, and various copper salts, analytical reagents and red glass. It can also be used in the rectifier plating in the electrical industry. It can also be used as the coloring agent for ceramic and enamel. 3. It can be used as analytical reagents and germicide. 4. It can be used as the reducing agent for determination of nitrogen content in azo compounds, red glaze, electroplating, germicide, red glass, ship bottom paint, plant seeds sterilization and catalyst.
DescriptionA widely used copper fungicide. It has a low aqueous solubility and a low volatility. As a heavy metal, copper itself will not degrade in the environment. It is moderately toxic to mammals and most biodiversity.
UsesCopper (I) oxide is used as red pigment for glass; in antifouling paints; fungicide.
UsesRed pigment for glass and ceramic glazes, and as a catalystCopper(I) oxide is used in antifouling, marine paint, brazing paste, antifungal treatment for plant seeds. Used as a hydrogen scavenger in copper brass and bronze and high grade lubricants. Finds uses in glass and ceramic pigments, ferrite magnets, catalyst in organic synthesis, dyes and dye intermediates and as catalysts.
UsesFungicide; antiseptic for fishnets; in antifouling paints for marine use; in photoelectric cells; as red pigment for glass, ceramic glazes; in brazing pastes; in rectifiers; as catalyst.
General DescriptionCopper(I) oxide is a weak inorganic base that can be used to activate halides for nucleophilic substitution reaction. It is also used in decarboxylation and cyclo condensation reactions.
Preparation methods
PreparationCopper(I) oxide decomposes above 1800°C but can be prepared by heating copper metal in air above 1030°C. To prevent further oxidation, the material must be cooled in an inert atmosphere. Lower temperatures may be used to produce the oxide if the material is blended with a reducing agent such as carbon and heated to 750°C in an inert atmosphere. The product must be stabilized with isophthalic acid or pine oil (Ayers, 1953). A particularly stable copper(I) oxide can be prepared by blending copper powder and cupric oxide in stoichiometric amounts and heating to 800-900°C. Lower temperatures can be used if ammonia or certain ammonium salts are added to the blend (Day, 1969; Drapeau and Johnson, 1956; Drapeau and Johnson, 1959).
Upstream & downstream products
Upstream raw materials
Downstream products
Suppliers100 total
Additional notes
DefinitionFor the native ore see cuprite.
DefinitionAn insoluble red powder prepared by the heating of copper with copper(II) oxide or the reduction of an alkaline solution of copper(II) sulfate. Copper(I) oxide is easily reduced by hydrogen when heated; it is oxidized to copper(II) oxide when heated in air. It is used in the glass industry. Copper( I) oxide undergoes disproportionation in acid solutions, producing copper(II) ions and copper. The oxide will dissolve in concentrated hydrochloric acid due to the formation of the complex ion [CuCl2]-. Copper(I) oxide is a covalent solid.
Related reactions
Compound notes
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