Dicopper oxide

HCID 14830

Basic information

CAS
1317-39-1
Standard SMILES
O.[Cu].[Cu]
InChIKey
LBJNMUFDOHXDFG-UHFFFAOYSA-N
Molecular formula
Cu2H2O
Average molar mass
145.11 g/mol
Monoisotopic mass
143.869759

Names & identifiers

Preferred name
Dicopper oxide
IUPAC
copper;hydrate
English name
Cuprous oxide
Molecular formula
Cu2O
Molecular weight
143.09

Names & synonyms

Dicopper oxideNordoxPerenoxCu-O-Cu LinkageCuprous oxide [ISO]CupriteCobre [Sandoz]Fungi-rhap Cu-75Kupferoxydul [German]Cupper oxide [Russian]Oxyde cuivreux [French]Copperoxy
Show more names
COPPER(I) OXIDECOPPER OXIDECupper oxideCopper oxide (Cu2O)Oxyde cuivreuxCopoxCu2-OCuprox
Oxyde cuivreux [ISO-French]Caocobre SandozPurple coppCCRIS 2289Cobre SandozCupron AHSDB 1549Dicopper monooxide

Database identifiers

CAS
1317-39-1
PubChem CID
14830
UNII
T8BEA5064F
Nikkaji
J95.201J

Properties

Computed structural properties

Topological polar surface area
1 Ų
Hydrogen bond donors
1
Hydrogen bond acceptors
1
Rotatable bonds
0
Heavy atoms
3

Physicochemical properties

Melting point
1232 °C · 1232 °C
Boiling point
1800 °C · 1800 °C
Density
6 g/mL · 6 g/mL at 25 °C (lit.)
refractive index
2.705 · 2.705
Flash point
1800 °C · 1800°C
storage temp.
Inert atmosphere,Room Temperature

Safety & regulation

Safety data

PPE
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
wgk
3
tsca
TSCA listed
rtecs
GL8050000
ridadr
UN 3077 9/PG 3
hs_code
28255000

Chemistry & industry

Applications · 6 items

Uses1. It can be used for coating of ship bottom coating, pesticide germicide, and glaze and used for copper oxide rectifier, photocell, electroplating and copper salt production. 2. It can be used in the manufacture of antifouling paint (used to kill low-level marine animals), pesticides, and various copper salts, analytical reagents and red glass. It can also be used in the rectifier plating in the electrical industry. It can also be used as the coloring agent for ceramic and enamel. 3. It can be used as analytical reagents and germicide. 4. It can be used as the reducing agent for determination of nitrogen content in azo compounds, red glaze, electroplating, germicide, red glass, ship bottom paint, plant seeds sterilization and catalyst.

DescriptionA widely used copper fungicide. It has a low aqueous solubility and a low volatility. As a heavy metal, copper itself will not degrade in the environment. It is moderately toxic to mammals and most biodiversity.

UsesCopper (I) oxide is used as red pigment for glass; in antifouling paints; fungicide.

UsesRed pigment for glass and ceramic glazes, and as a catalystCopper(I) oxide is used in antifouling, marine paint, brazing paste, antifungal treatment for plant seeds. Used as a hydrogen scavenger in copper brass and bronze and high grade lubricants. Finds uses in glass and ceramic pigments, ferrite magnets, catalyst in organic synthesis, dyes and dye intermediates and as catalysts.

UsesFungicide; antiseptic for fishnets; in antifouling paints for marine use; in photoelectric cells; as red pigment for glass, ceramic glazes; in brazing pastes; in rectifiers; as catalyst.

General DescriptionCopper(I) oxide is a weak inorganic base that can be used to activate halides for nucleophilic substitution reaction. It is also used in decarboxylation and cyclo condensation reactions.

Preparation methods · 1 item

PreparationCopper(I) oxide decomposes above 1800°C but can be prepared by heating copper metal in air above 1030°C. To prevent further oxidation, the material must be cooled in an inert atmosphere. Lower temperatures may be used to produce the oxide if the material is blended with a reducing agent such as carbon and heated to 750°C in an inert atmosphere. The product must be stabilized with isophthalic acid or pine oil (Ayers, 1953). A particularly stable copper(I) oxide can be prepared by blending copper powder and cupric oxide in stoichiometric amounts and heating to 800-900°C. Lower temperatures can be used if ammonia or certain ammonium salts are added to the blend (Day, 1969; Drapeau and Johnson, 1956; Drapeau and Johnson, 1959).

Suppliers100 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]
Additional notes · 2 items

DefinitionFor the native ore see cuprite.

DefinitionAn insoluble red powder prepared by the heating of copper with copper(II) oxide or the reduction of an alkaline solution of copper(II) sulfate. Copper(I) oxide is easily reduced by hydrogen when heated; it is oxidized to copper(II) oxide when heated in air. It is used in the glass industry. Copper( I) oxide undergoes disproportionation in acid solutions, producing copper(II) ions and copper. The oxide will dissolve in concentrated hydrochloric acid due to the formation of the complex ion [CuCl2]-. Copper(I) oxide is a covalent solid.

Related reactions

1 records

Compound notes

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