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Copper monosulfide

HCID 14831
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Basic information

CAS
1317-40-4
Standard SMILES
[S]=[Cu]
InChIKey
BWFPGXWASODCHM-UHFFFAOYSA-N
Molecular formula
CuS
Average molar mass
95.61 g/mol
Monoisotopic mass
94.9016685

Overview

Covellite is a mineral with formula of Cu1+S or CuS. The IMA symbol is Cv.

Names & identifiers

Preferred name
Copper monosulfide
IUPAC
sulfanylidenecopper
English name
COPPER(II) SULFIDE
Molecular formula
CuS
Molecular weight
95.61

Names & synonyms

Copper monosulfideCopper sulphideCopper(ii)sulfide19138-68-2Covellite (CuS) (9CI)CovelliteCovellineCovellite (CuS)HSDB 5805EINECS 215-271-2NSC 47694UNII-KL4YU612X7
Show more names
CuSCOPPER SULFIDECUPRIC SULFIDEOil BlueC.I. 77450Copper BlueCUPRIC SULPHIDE
AI3-51685(Sulfido)copperSCHEMBL724Copper sulfide, 99.5%EC 215-271-2Copper(II) sulfide, ultra dryDTXSID601316949NSC47694

Database identifiers

CAS
1317-40-4、19138-68-2
PubChem CID
14831
DTXSID
DTXSID601316949
Nikkaji
J43.800F

Properties

Computed structural properties

Topological polar surface area
32.1 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
1
Rotatable bonds
0
Heavy atoms
2
Formal charge
0
Complexity
2

Physicochemical properties

Melting point
220 °C · 220 °C (dec.) (lit.)
Density
4.6 g/mL · 4.6 g/mL at 25 °C (lit.)
refractive index
1.45 · 1.45
solubility
2 O, · insoluble in H2O, ethanol, dilacid, alkaline solutions
form
powder
color
Black
Specific Gravity
4.6 · 4.6 (20℃)
Water Solubility
Soluble in nitric acid, ammonium hydroxide, potassium cyanide. Insoluble in water, ethanol, hydrochloric acid ,dilute acids, sulfuric acid, alkali cyanides, aqueous ammonia and alkaline solutions.
Specific Heat Capacity
0.5 J/ · Cp(crystal): 0.5 J/(g·K), at 25℃
Sensitive
Air & Moisture Sensitive
Merck
14 · 14,2965
crystal system
Six sides
Space group
63 · P63/mmc
Solubility Product Constant (Ksp)
35.2 · pKsp: 35.2
Lattice constant
a/nm

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

PPE
Eyeshields, Gloves, type N95 (US)
wgk
3
tsca
TSCA listed
rtecs
GL8912000
hs_code
2830908500
safety_code
22-24/25
Storage Class
11 - Combustible Solids
Hazard statements
H413
REACH Registrations
Active
Hazardous Substances Data
1317-40-4(Hazardous Substances Data)

Chemistry & industry

Applications · 3 items

UsesCopper(II) sulfide is used in antifouling paints, mixed catalysts and to develop aniline black dyes in textile printing. Further, it is used as a varnish pigment and an oxidizing agent. In addition, it is used as a component of solid state electrodes and thin-film solar cell with cadmium sulfide. It is a moderate conductor of electricity and used in photovoltaics.

UsesIn antifouling paints; in preparation of mixed catalysts; in development of aniline black dye in textile printing.

General DescriptionCu63 NMR, X ray photoelectron spectroscopy,2 copper sulfide CuS was studied in detail.

Preparation methods · 1 item

PreparationCopper(II) sulfide is prepared by heating copper(I) sulfide in the presence of excess sulfur in a hydrogen atmosphere. Ethanol solutions of anhydrous copper(II) chloride precipitate the copper(II) sulfide on the addition of hydrogen sulfide.

Upstream & downstream products

Downstream products

Copper(II) sulfate pentahydrateCopper(II) sulfate

Additional notes

DefinitionChEBI: Copper(II) sulfide is a copper sulfide in which the metal is in the +2 oxidation state.

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Related reactions

2 records
New reaction record
HRID 611068 reaction equation
HRID 611068As catalystuspto-grants-1999_12
HRID 1588945 reaction equation
HRID 1588945As catalystuspto-grants-1993_06

Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Hazard statements
413 · H413
PPE
95 · Eyeshields, Gloves, type N95 (US)
Safety Statements
22 · 22-24/25
WGK Germany
3 · 3
RTECS
8912000 · GL8912000
TSCA
TSCA listed
HS Code
2830908500 · 2830908500
Storage Class
11 · 11 - Combustible Solids
Hazardous Substances Data
1317 · 1317-40-4(Hazardous Substances Data)
REACH Registrations
Active