Methyl 2-chloropropanoate, (R)- (HCID 149593)

Names & identifiers

Preferred name: Methyl 2-chloropropanoate, (R)-
IUPAC: methyl (2R)-2-chloropropanoate
English name: (R)-(+)-Methyl (R)-2-chloropropionate
Molecular formula: C4H7ClO2
Molecular weight: 122.55

Names & synonyms

77287-29-7Methyl (R)-2-chloropropionate(R)-(+)-2-Chloropropionic acid methyl esterCCRIS 7388(R)-2-Chloropropanoic acid methyl esterPropanoic acid, 2-chloro-, methyl ester, (2R)-EINECS 278-658-5Methyl 2-chloropropanoate, (R)-89L56A505XDTXSID901032960(+)-METHYL 2-CHLOROPROPANOATEMETHYL D-.ALPHA.-CHLOROPROPIONATE

Show more names

methyl (R)-2-chloropropanoateUNII:FDN17EXK1J2 METHYL CHLORPROPIONATE2-Methylchlorproprionate2-Methylchloroproprionate(R)-Methyl 2-chloropropanoatemethyl (2R)-2-chloropropanoate(R)-2-Chloropropionic acid methyl(R)-(+)-METHYL 2-CHLOROPROPIONATE

METHYL 2-CHLOROPROPANOATE, (+)-(+)-METHYL .ALPHA.-CHLOROPROPIONATE(-)-Methyl (S)-2-chloropropionate(+)-Methyl 2-chloropropionateRefChem:814324DTXCID101517988METHYL D-ALPHA-CHLOROPROPIONATE(+)-METHYL ALPHA-CHLOROPROPIONATE

Database identifiers

CAS: 73246-45-4、77287-29-7
PubChem CID: 149593
DTXSID: DTXSID901032960
UNII: 89L56A505X
EC Number: 278-658-5、625-379-5
Nikkaji: J56.929A

Properties

Computed structural properties

XLogP: 1.1
Topological polar surface area: 26.3 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 2
Rotatable bonds: 2
Heavy atoms: 7
Formal charge: 0
Complexity: 72.1

Physicochemical properties

alpha: 26 · 26 º (neat)
Boiling point: 132 · 132-134 °C(lit.)
Density: 1.152 g/mL · 1.152 g/mL at 25 °C(lit.)
refractive index: 20 · n20/D 1.418
Flash point: 99 °F · 99 °F
form: clear liquid
color: Colorless to Almost colorless
optical activity: 20 · [α]20/D +26°, neat
BRN: 1720590 · 1720590
InChI: 1S/C4H7ClO2/c1-3(5)4(6)7-2/h3H,1-2H3/t3-/m1/s1
InChIKey: JLEJCNOTNLZCHQ-GSVOUGTGSA-N
SMILES: COC(=O)[C@@H](C)Cl
CAS DataBase Reference: 77287 · 77287-29-7(CAS DataBase Reference)
FDA UNII: 89 L56A505X · 89L56A505X
UNSPSC Code: 12352101 · 12352101
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS07
Signal word: Warning
Hazard statements: 315 · H315-H319-H226
Precautionary statements: 501 · P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235
target organs: Respiratory system
PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes: Xi
Risk Statements: 10 · 10-36/37/38
Safety Statements: 26 · 26-36
RIDADR: 2933 · UN 2933 3/PG 3
WGK Germany: 3 · 3
F: 19 · 19
HazardClass: 3 · 3
PackingGroup: III
HS Code: 29159000 · 29159000
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 2 Flam · Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
Limited Quantities: 5 L · 5.0 L (1.3 gallons) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Safety & regulation

GHS classification

GHS Classification · 6 items

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264+P265, P280, P303+P361+P353, P305+P351+P338, P319, P337+P317, P370+P378, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

Hazard information

Hazard Classes and Categories · 2 items

Flam. Liq. 3 (100%)

Safety data

F: 19
PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk: 3
ridadr: UN 2933 3/PG 3
hs_code: 29159000
risk_code: 10-36/37/38
Signal word: Warning
Symbol(GHS): GHS02,GHS07
hazard_code: Xi
safety_code: 26-36
hazard_class: 3
Storage Class: 3 - Flammable liquids
packing_group: III
target organs: Respiratory system
Hazard statements: H315-H319-H226
Limited Quantities: 5.0 L (1.3 gallons) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
Precautionary statements: P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235