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Nickel-63(II) chloride

HCID 158404
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Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
7718-54-9
Standard SMILES
[Cl-].[Cl-].[Ni+2]
InChIKey
QMMRZOWCJAIUJA-UHFFFAOYSA-L
Molecular formula
Cl2Ni
Average molar mass
129.6 g/mol
Monoisotopic mass
127.873047

Overview

See also: Nickel Dichloride (preferred).

Names & identifiers

Preferred name
Nickel-63(II) chloride
IUPAC
nickel(2+) dichloride
English name
Nickle chloride
Molecular formula
Cl2Ni
Molecular weight
129.6

Names & synonyms

Cl2NiNickel-63(II) chloride83864-14-663-Nickel chloride63-Nickel dichloridenickel(2+) dichlorideNickel chloride (63NiCl2)SCHEMBL24279NICKEL CHLORIDE [MI]NICKEL CHLORIDE [HSDB]Tox21_302175s12327
Show more names
NiCl2NiClNICKEL DICHLORIDENICKEL CHLORIDENICKEL(II) CHLORIDEHexahydratedichloronickelLiCl2.6H2ONichel chloride
NCGC00255504-01CAS-7718-54-9N0850N0851NS00089276F494386

Database identifiers

CAS
7718-54-9、83864-14-6
PubChem CID
158404
DTXSID
DTXSID7040316
UNII
696BNE976J
Nikkaji
J3.106B

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
0

Physicochemical properties

Melting point
1001 °C · 1001 °C
Boiling point
987 °C · 987°C
Density
3.55 g/mL · 3.55 g/mL at 25 °C(lit.)
vapor pressure
1.33 hPa · 1.33 hPa (671 °C)
storage temp.
30 °C · Store below +30°C.
solubility
2 O: · H2O: soluble
form
powder
color
Yellow to orange
Specific Gravity
3.55 · 3.55
PH
4 · 4 (500g/l, H2O, 20℃)
Water Solubility
slightly soluble
Specific Heat Capacity
0.55 J/ · Cp(crystal): 0.55 J/(g·K), at 25℃
Crystal Structure
2 type · CdCl2 type
Sensitive
Hygroscopic
Merck
14 · 14,6505
crystal system
Three sides
Space group
3 m · R3m

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

F
3
PPE
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
3
tsca
TSCA listed
rtecs
QR6475000
ridadr
UN 3288 6.1/PG 3
hs_code
28273500
Toxicity
LD50 in mice, rats (mg/kg): 48, 11 i.p. (IARC)
risk_code
45-25-36/38-43-50-50/53-22-52/53-68-51/53-48/23-42/43-20/22-61-49-38-23/25
Signal word
Danger
Symbol(GHS)
GHS06,GHS08,GHS09
hazard_code
T,N,Xi
safety_code
53-26-36/37-45-61-37-29-24-23-60
hazard_class
6.1(b)
Storage Class
6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
packing_group
III
target organs
Lungs
Hazard statements
H301+H331-H315-H319-H360-H371-H372-H317-H334-H341-H350-H410
Limited Quantities
5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations
Active
Hazard Classifications
Acute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1A InhalationMuta. 2Repr. 1BResp. Sens. 1Skin Irrit. 2Skin Sens. 1STOT RE 1 Inhalation
Precautionary statements

Chemistry & industry

Applications · 6 items

DescriptionNickel chloride is a brown or green colored solid. Most nickel chloride is used for electroplating and nickel plating, used to prepare various nickel salts and nickel catalysts; . During electroplating, it accelerates the dissolution of anode metal nickel, while acting to increase the electrolyte level of the solution. Nickel chloride can be used as catalyst for organic synthesis (e.g. pyrazolophthalazinyl spirooxindoles), to synthesize nickel nanoparticles as a reductant, and to prepare nickel coordination compounds, and and in industrial gas masks to protect from ammonia. It can also be used as an NH3 absorbent in gas masks and as a source of nickel ion for cell culture and toxicological studies.

DescriptionNickel chloride, NiCl2, is a water-soluble salt used in a variety of industries. It is typically produced and used either as an anhydrous salt or as a hydrate: nickel chloride hexahydrate as well as nickel chloride dihydrate. Nickel chloride is very rarely found in nature, and is produced via extraction from nickelcontaining ores via treatment with hydrochloric acid.

UsesNickel chloride (NiCl2) is used for electroplating nickel onto the surfaces of other metals and as a chemical reagent in laboratories.

UsesNickel chloride is used for nickel plating cast zinc, as an agent in electrolytic refining of nickel, as a chemical intermediate for nickel catalysts and complex nickel salts, as an absorber of ammonia gas in industrial gas masks, as a catalyst in diarylamine and silicon tetrachloride production, as an agent in electrodeless plating of nickel, as an agent in tin–nickel alloy plating, and as a fungicide for control of rust and rustlike disease. However, workers exposed to different forms of nickel have an elevated risk of lung cancer. Besides, Ni and its compounds (particularly insoluble compounds of nickel) have been reported to be potent carcinogens and toxic agents in humans and experimental animals. Therefore, Ni compounds are considered to be an industrial/occupational health hazard.

UsesNickel chloride solutions are used for electroplating nickel onto other metal items.It also is used to prepare various nickel salts and nickel catalysts; and in industrial gas masks to protect from ammonia.

General DescriptionNickel(II) chloride (NiCl2) is a nickel based halide that is prepared by burning nickel in chlorine. It is a water soluble compound that crystallizes to form a hexahydrate. It is majorly utilized in organic synthesis as a catalyst and a precursor.

Related reactions

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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
More actions
New noteNew reactionRequest quotes
Lattice constant
a/nm
Symbol(GHS)
6 · GHS06,GHS08,GHS09
Signal word
Danger
Hazard statements
301 · H301+H331-H315-H319-H360-H371-H372-H317-H334-H341-H350-H410
Precautionary statements
501 · P501-P273-P272-P260-P270-P202-P201-P271-P264-P280-P284-P302+P352-P391-P337+P313-P305+P351+P338-P308+P311-P362+P364-P333+P313-P301+P310+P330-P304+P340+P311-P403+P233-P405
target organs
Lungs
PPE
3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes
T,N,Xi
Risk Statements
45 · 45-25-36/38-43-50-50/53-22-52/53-68-51/53-48/23-42/43-20/22-61-49-38-23/25
Safety Statements
53 · 53-26-36/37-45-61-37-29-24-23-60
RIDADR
3288 · UN 3288 6.1/PG 3
WGK Germany
3 · 3
RTECS
6475000 · QR6475000
F
3 · 3
TSCA
TSCA listed
HazardClass
6.1 · 6.1(b)
PackingGroup
III
HS Code
28273500 · 28273500
Storage Class
6.1 D · 6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
Hazard Classifications
3 InhalationAcute · Acute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1A InhalationMuta. 2Repr. 1BResp. Sens. 1Skin Irrit. 2Skin Sens. 1STOT RE 1 Inhalation
Hazardous Substances Data
7718 · 7718-54-9(Hazardous Substances Data)
Toxicity
50 in · LD50 in mice, rats (mg/kg): 48, 11 i.p. (IARC)
REACH Registrations
Active
Limited Quantities
5 kg · 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
P501-P273-P272-P260-P270-P202-P201-P271-P264-P280-P284-P302+P352-P391-P337+P313-P305+P351+P338-P308+P311-P362+P364-P333+P313-P301+P310+P330-P304+P340+P311-P403+P233-P405
Hazardous Substances Data
7718-54-9(Hazardous Substances Data)
Preparation methods · 2 items

PreparationAnhydrous nickel chloride is prepared by burning nickel in chlorine gas. Some other methods of preparation involve (1) the action of acetyl chloride on nickel acetate in a nonaqueous solvent such as benzene: (CH3COO)2Ni + 2CH3COCl → NiCl2 + 2CH3COOCOCH3 (2) the action of thionyl chloride on nickel chloride hexahydrate: NiCl2•6H2O + 6SOCl2 → NiCl2 + 12HCl + 6SO2 (3) heating nickel chloride hexahydrate or nickel chloride ammoniate: NiCl2•6H2O → NiCl2 + 6H2O NiCl2•6NH3 → NiCl2 + 6NH3 The hexahydrate is prepared either by the action of hot dilute hydrochloric acid on nickel powder or by dissolving nickel oxide in dilute hydrochloric acid followed by crystallization. For the preparation of ammoniate, see Reactions below.

PreparationNickel(II) chloride can be obtained by reaction of the elements either in a flow system at high temperatures or by reaction in ethanol at 20°. It is readily prepared in the laboratory by dehydration of the hexahydrate with thionyl chloride.

Upstream & downstream products

Upstream raw materials

Nickel carbonateNickelHydrochloric acidNickel sulfateNitric acidSulfuric acidSodium carbonate

Downstream products

Nickel(II) chloride hexahydrateNickel(II) nitrate hexahydrateNickel dibutyldithiocarbamate(1,3-Dimethyl-1H-pyrazol-5-yl)methylamine2-(1,3-Dimethyl-1H-pyrazol-5-yl)ethanamine ,97%(1,5-Dimethyl-1H-pyrazol-3-yl)methylamine(4-(4-[Bis(4-fluorophenyl)methyl]piperazin-1-yl)phenyl)methanol
Additional notes · 2 items

DefinitionChEBI: A compound of nickel and chloride in which the ratio of nickel (in the +2 oxidation state) to chloride is 1:2. Nickel chloride is a yellow deliquescent solid with a boiling point of 973°C(1690°F). Nickel chloride is soluble in water and alcohol. Nickel chloride(hydrated),NiCI2·H20, is a gray deliquescent solid that is also soluble in water and alcohol.It is used in nickel plating.

Definitionhexahydrate: A crystalline compoundthat has six moles of waterper mole of compound.