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Methanesulfonic acid, silver(1+) salt (1:1)

HCID 159658
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Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
2386-52-9
Standard SMILES
CS(=O)(=O)[O-].[Ag+]
InChIKey
MLKQJVFHEUORBO-UHFFFAOYSA-M
Molecular formula
CH3AgO3S
Average molar mass
202.967 g/mol
Monoisotopic mass
201.88538696

Names & identifiers

Preferred name
Methanesulfonic acid, silver(1+) salt (1:1)
IUPAC
Silver(1+) methanesulfonate
English name
Silver mesylate
Molecular formula
CH3AgO3S
Molecular weight
202.97

Names & synonyms

SMSSILVER METHANESULFONATEMRSRSPMSYSILVER MESYLATESilver Mesylate 99%Silver methylsulfonatesilver methanesulphonatemethanesulfonylacidsilverSilver(I) methanesulfonate

Database identifiers

CAS
2386-52-9
PubChem CID
159658
DTXSID
DTXSID60883836
EC Number
219-199-2
Nikkaji
J41.680K

Properties

Physicochemical properties

Melting point
252 · 252-256 °C (lit.)
Density
1.405 at · 1.405 at 20℃
storage temp.
Keep in dark place,Inert atmosphere,Room temperature
form
Powder
color
White to beige or light gray
PH
1 at · 1 at 20℃ and 10g/L
Water Solubility
Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane.
Sensitive
Light Sensitive
InChI
InChI=1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
InChIKey
MLKQJVFHEUORBO-UHFFFAOYSA-M
SMILES
S([O-])(=O)(=O)C.[Ag+]
Surface tension
77.8 mN/m · 77.8mN/m at 1g/L and 20℃
Dissociation constant
1.9 at · 1.9 at 20℃
CAS DataBase Reference
2386 · 2386-52-9(CAS DataBase Reference)
EPA Substance Registry System
Methanesulfonic acid, silver(1+) salt (2386-52-9)
UNSPSC Code
12161600 · 12161600
NACRES
22 · NA.22
Symbol(GHS)
7 · GHS07
Signal word
Warning
Hazard statements
315 · H315-H319-H335
Precautionary statements
261 · P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs
Respiratory system

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

PPE
dust mask type N95 (US), Eyeshields, Gloves
wgk
3
tsca
TSCA listed
rtecs
PB2685000
ridadr
1759
hs_code
28432900
risk_code
36/37/38-20/21/22
Signal word
Warning
Symbol(GHS)
GHS07
hazard_code
Xi,Xn
safety_code
26-36-36/37/39-22
hazard_class
8
Storage Class
11 - Combustible Solids
packing_group
III
target organs
Respiratory system
Hazard statements
H315-H319-H335
REACH Registrations
Active
Hazard Classifications
Eye Irrit. 2Skin Irrit. 2STOT SE 3
Precautionary statements
P261-P264-P271-P280-P302+P352-P305+P351+P338

Chemistry & industry

Applications

UsesSilver methanesulfonate is used as a catalyst for heterocyclization reactions. Further, it is used in the synthesis of unsaturated ketones and esters.

UsesGold Catalysts—21st Century'Gold Rush' Catalyst for: .Heterocyclization reactions . CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,-unsaturated ketones and esters

Upstream & downstream products

Upstream raw materials

Silver oxideMethanesulfonic acid

Downstream products

tributylstannyl methanesulfonateAcetic acid, 2-[(methylsulfonyl)oxy]-

Suppliers100 total

阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
湖北宥澄新材料科技有限公司17764017698 13163370568 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]

Related reactions

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Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
PPE
95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
Xi,Xn
Risk Statements
36 · 36/37/38-20/21/22
Safety Statements
26 · 26-36-36/37/39-22
RIDADR
1759 · 1759
WGK Germany
3 · 3
RTECS
2685000 · PB2685000
TSCA
TSCA listed
HazardClass
8 · 8
PackingGroup
III
HS Code
28432900 · 28432900
Storage Class
11 · 11 - Combustible Solids
Hazard Classifications
2 Skin · Eye Irrit. 2Skin Irrit. 2STOT SE 3
REACH Registrations
Active
河南多贝化工有限公司
0370-6999054 17550096163 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
毕佳索(上海毕得医药科技股份有限公司)400-6005915 · [email protected]
郑州德元凯化工有限公司17837139533 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
北京华威锐科化工有限公司0757-86329057 18934348241 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
上海柏卡化学技术有限公司400-026-1533/(021) 6478-0600 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
上海钰康生物科技有限公司+86-18930848214 +86-021-56762820 · [email protected]
嘉兴市艾森化工有限公司0573-85285100 18627885956 · [email protected]
湖北广奥生物科技有限公司027-02702759223056 18162699093 · [email protected]
湖北成海化工有限公司027-59220433 18327245847 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
广东大小化工有限公司171603 18666171603 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
南京化学试剂股份有限公司025-58369808 17895012682 · [email protected]
南京辛西亚生物科技有限公司0550-5618439 15951861180 · [email protected]
上海和宁美生物医药科技有限公司021-18019086215 18019086215 · [email protected]
赛默飞世尔科技(中国)有限公司800-810-5118 · [email protected]
北京伊诺凯科技有限公司400-810-7969 010-59572699 · [email protected]
上海健超生物科技有限公司150-2103-5486 18017383231 · [email protected]
广东顺奥化学试剂有限公司19928586137 · [email protected]
南京拉瑞创新科技有限公司025-83726959 15851816062 · [email protected]
南京毕科生物科技有限公司025-58906079 15151970915 · [email protected]
苏州爱玛特生物科技有限公司0512-56316828 4008675858 · [email protected]
上海湄水化工科技有限公司021-60549325 18616193163
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]
上海毕得医药科技股份有限公司400-164-7117 18317119277 · [email protected]
上海笛柏生物科技有限公司400-008-9730,021-54359730 400-008-9730 · [email protected]
重庆星灿医药科技有限公司13594048950 19923294409 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
杭州杰恒化工有限公司0571-87396432 · [email protected]
湖北巨胜科技有限公司027-59599241 18871490274 · [email protected]
池州凯隆进出口贸易有限公司[email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
海南瀚海致远生物科技有限公司18171012772 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
Henan Alfa Chemical Co., Ltd+8618339805032 · [email protected]
上海谱振生物科技有限公司4001650900 13817534909 · [email protected]
厦门志信化学有限公司+86-5922680277 +86-13806087780 · [email protected]
陕西瑞和明生物科技有限公司029-62584593 15029880552 · [email protected]