Dipotassium pentachloronitrosylruthenate
Basic information
- CAS
14854-54-7- Standard SMILES
N#[O+].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[K+].[K+].[Ru+2]- InChIKey
WNVHAHDPZULZJL-UHFFFAOYSA-I- Molecular formula
- Cl5K2NORu
- Average molar mass
- 386.5 g/mol
- Monoisotopic mass
- 384.674005
Overview
a water soluble, thermally stable and NO-donor compound
Names & identifiers
- Preferred name
- Dipotassium pentachloronitrosylruthenate
- IUPAC
- dipotassium;azanylidyneoxidanium;ruthenium(2+);pentachloride
- English name
- POTASSIUM PENTACHLORONITROSYLRUTHENATE(II)
- Molecular formula
- Cl5KNORu-
- Molecular weight
- 347.42
Names & synonyms
Dipotassium pentachloronitrosylruthenateRefChem:134819K2 Ru(NO)Cl5DTXCID40227754DTXSID70276472potassium nitrosylpentachlororuthenate238-919-6Potassium pentachloronitrosyl ruthenate(II)dipotassium;azanylidyneoxidanium;ruthenium(2+);pentachlorideRuthenate(2-), pentachloronitrosyl-, potassium (1:2), (OC-6-21)-698980-38-0EINECS 238-919-6
Show more names
Potassium pentachloronitrosylruthenate(IV)nitroxyl anionCAGED NITRIC OXIDE Ipentachlororuthenium(2-)RUTHENIUM POTASSIUM NITROSO CHLORIDEPotassium pentachloronitrosylruthenate(Ⅱ)Potassium pentachloronitrosylruthenate(Ⅱ)POTASSIUM PENTACHLORONITROSYLRUTHENATE(II)
Cl5K2NORuPotassium pentachloronitrosylruthenate (II)Potassium nitrosyl pentachlororuthenate(III)Ruthenate(2+), nitrosylpentachloro-, dipotassium hydrateFCWXUHRWZLOTGH-UHFFFAOYSA-IAKOS015915916Potassiumpentachloronitrosylruthenate(II)AS-89651
Properties
Computed structural properties
- Topological polar surface area
- 24.8 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 0
- Heavy atoms
- 10
- Formal charge
- 0
- Complexity
- 10
Physicochemical properties
- Melting point
- 220 °C · 220 °C (dec.) (lit.)
- form
- Crystalline
- Water Solubility
- Soluble in water.
- InChI
- 1S/5ClH.2K.NO.Ru/c;;;;;;;1-2;/h5*1H;;;;/q;;;;;2*+1;-1;+4/p-5
- InChIKey
- WNVHAHDPZULZJL-UHFFFAOYSA-I
- SMILES
- [K+].[K+].Cl[Ru--](Cl)(Cl)(Cl)(Cl)N=O
- CAS DataBase Reference
- 14854 · 14854-54-7
- EPA Substance Registry System
- Ruthenate(2-), pentachloronitrosyl-, dipotassium (14854-54-7)
- UNSPSC Code
- 12352302 · 12352302
- NACRES
- 23 · NA.23
- Symbol(GHS)
- 7 · GHS07
- Signal word
- Warning
- Hazard statements
- 315 · H315-H319-H335
- Precautionary statements
- 261 · P261-P264-P271-P280-P302+P352-P305+P351+P338
- target organs
- Respiratory system
- PPE
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 43 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazard Classes and CategoriesSkin Irrit. 2 (100%)
Safety data
- PPE
- dust mask type N95 (US), Eyeshields, Gloves
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- VM2640000
- Toxicity
- mouse,LD50,intraperitoneal,127mg/kg (127mg/kg),BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSIONBEHAVIORAL: COMA,Journal of Toxicology and Environmental Health. Vol. 6, Pg. 757, 1980.
- risk_code
- 36/37/38
- Signal word
- Warning
- Symbol(GHS)
- GHS07
- hazard_code
- Xi
- safety_code
- 26-36
- Storage Class
- 11 - Combustible Solids
- target organs
- Respiratory system
- Hazard statements
- H315-H319-H335
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationRuthenate(2-), pentachloronitrosyl-, potassium (1:2), (OC-6-21)-: INACTIVE
Applications
UsesUsed as precipitation agent in Heterobimetallic coordination polymers involving 3d metal complexes and heavier transition metals cyanometallates. Ruthenium complexes are presently an object of great attention in the field of medicinal chemistry, as antitumor agents with selective antimetastatic properties and low systemic toxicity. Ruthenium compounds appear to penetrate reasonably well the tumor cells and bind effectively to DNA.
Related reactions
0 records
No reaction records under the current filter.
Compound notes
Loading…