Basic information
- CAS
1931-62-0- Standard SMILES
CC(C)(C)OOC(=O)C=CC(=O)O- InChIKey
RQHGZNBWBKINOY-UHFFFAOYSA-N- Molecular formula
- C8H12O5
- Average molar mass
- 188.18 g/mol
- Monoisotopic mass
- 188.06847348
Overview
This solid peroxide is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide with an inert solid.
Names & identifiers
- Preferred name
- Tert-butyl monoperoxymaleate
- IUPAC
- 4-tert-butylperoxy-4-oxobut-2-enoic acid
- English name
- PERKADOX PF-DBM25
- Molecular formula
- C8H12O5
- Molecular weight
- 188.18
Names & synonyms
TERT-BUTYL PEROXYMALEATE, (TECHNICALLY PURE)TERT-BUTYL PEROXYMALEATE, [TECHNICALLY PURE]tert-butyl monoperoxymaleateMaleic monoperoxyacid, 1-tert-butyl esterRefChem:894679PERBUTYL MA 25tert-butyl peroxymaleic acidTERT-BUTYL MONOPERMALEATE2-Propeneperoxoic acid, 3-carboxy-, 1-(1,1-dimethylethyl) ester, (Z)-MALEIC MONOPEROXYACID, OO-TERT-BUTYL ESTER4-tert-butylperoxy-4-oxobut-2-enoic acid1931-62-0
Show more names
OO-tert-butyl monoperoxymaleateTBPMAPERKADOX PF-DBM25tert-Butyl permaleateButyl maleate peroxideDi-tert-butylperoxymaleatet-Butyl peroxy maleic acid
4-tert-butyldioxy-4-oxo-2-butenoateSCHEMBL3878187DTXSID20862788NS000457004-(TERT-BUTYLPEROXY)-4-OXOBUT-2-ENOIC ACID24491-54-1
Database identifiers
Properties
Computed structural properties
- XLogP
- 0.9
- Topological polar surface area
- 72.8 Ų
- Hydrogen bond donors
- 1
- Hydrogen bond acceptors
- 5
- Rotatable bonds
- 5
- Heavy atoms
- 13
- Formal charge
- 0
- Complexity
- 223
Experimental & physicochemical properties
Physical DescriptionThis solid peroxide is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide with an inert solid.
Physicochemical properties
- Melting point
- 130 · 130-131 °C
- Boiling point
- 260.8 · 260.8±42.0 °C(Predicted)
- Density
- 1.185 · 1.185±0.06 g/cm3(Predicted)
- vapor pressure
- 0.147 Pa · 0.147Pa at 25℃
- storage temp.
- Flammables area
- pka
- 2.38 · 2.38±0.25(Predicted)
- form
- Solid
- Water Solubility
- 642 mg/L · 642mg/L at 20℃
- LogP
- 0.9 at · 0.9 at 30℃
- CAS DataBase Reference
- 1931 · 1931-62-0
- EPA Substance Registry System
- 2 · 2-Propeneperoxoic acid, 3-carboxy-, 1-(1,1-dimethylethyl) ester, (2Z)- (1931-62-0)
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H317: May cause an allergic skin reaction [Warning Sensitization, Skin]
P261, P264+P265, P272, P273, P280, P302+P352, P305+P354+P338, P317, P321, P333+P317, P362+P364, and P501 (click each P-code to see the statement)
Danger
H241: Heating may cause a fire or explosion [Danger Self-reactive substances and mixtures; Organic peroxides]
P210, P234, P235, P240, P280, P370+P380+P375[+P378], P403, P410, P411, P420, and P501 (click each P-code to see the statement)
Hazard information
DOT LabelOrganic Peroxide
Fire HazardsExcerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Health HazardsExcerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Reactive GroupAcids, Carboxylic
Reactivity AlertsExplosive
Reactivity ProfileTERT-BUTYL MONOPEROXYMALEATE explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602].
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and Categories
Organic peroxides - Type B
Serious eye damage/eye irritation - Category 1
Chemistry & industry
Applications
General DescriptionPERKADOX PF-DBM25 is sensitive to heat. Storage of PERKADOX PF-DBM25 must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide with an inert solid.
Suppliers29 total
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
南通合润生物科技有限公司18362409333 · [email protected]
武汉赛沃尔化工有限公司027-85613400 18707177243 · [email protected]
赛默飞世尔科技（中国）有限公司800-810-5118 · [email protected]
上海丽康新材料有限公司+86-16631818819 +86-17736933208 · [email protected]
PT CHEM GROUP LIMITED+86-85511178; +86-85511178 · [email protected]
天津荣燊化工有限公司18317763565; 18317763565 · [email protected]
Related reactions
0 records
No reaction records under the current filter.
Compound notes
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