Phosphomolybdic acid hydrate

HCID 16211564CAS 11104-88-4

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Basic information

Standard SMILES: O.O=P(O)(O)O.[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O]
Molecular formula: H3Mo12O41P-2
Average molar mass: 1,841.36 g/mol

Names & identifiers

Preferred name: Phosphomolybdic acid hydrate
English name: Phosphomolybdic acid hydrate
Molecular formula: H3Mo12O41P-2
Molecular weight: 1841.36

Names & synonyms

PHOSPHOMOLYBDIC ACIDPHOSPHOMOLYBDIC ACID HYDRATEMOLYBDATOPHOSPHORIC ACID HYDRATE72.0 %bdicAcidPhosphomoLybdic Acid HydratePhosphomolybdic AciPMA Ethanol SolutionPhosphomolybdicAcidGr

Database identifiers

CAS: 11104-88-4、12026-57-2、51429-74-4
PubChem CID: 16211564
UNII: RN225F04V1
EC Number: 610-660-7

Properties

Physicochemical properties

Melting point: 78 · 78-90°C
Density: 1.62 g/mL · 1.62 g/mL at 25 °C(lit.)
bulk density: 980 kg/m3 · 980kg/m3
Flash point: 12 ° · 12°
storage temp.: 5 °C · Store at +5°C to +30°C.
solubility: Water (Slightly)
form: Solid
Specific Gravity: 0.94 · 0.94
color: Yellow
Water Solubility: Soluble in water, ethanol and ether.
Sensitive: Hygroscopic
Merck: 14 · 14,7342
Exposure limits: 0.5 mg/m3NIOSH: · ACGIH: TWA 0.5 mg/m3NIOSH: IDLH 1000 mg/m3
Stability: Stable. Incompatible with powdered metals, organic materials. Contact with combustible material may cause fire.
InChI: 1S/12Mo.H3O4P.H2O.36O/c;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;
InChIKey: YBJOGPJTURREAY-UHFFFAOYSA-L
CAS DataBase Reference: 51429 · 51429-74-4(CAS DataBase Reference)
FDA UNII: 225 F04V1 · RN225F04V1
UNSPSC Code: 12352301 · 12352301
NACRES: 21 · NA.21
Symbol(GHS): 3 · GHS03,GHS05
Signal word: Danger
Hazard statements: 272 · H272-H314
Precautionary statements: 210 · P210-P220-P260-P280-P303+P361+P353-P305+P351+P338
PPE: 3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes: O,C
Risk Statements: 8 · 8-34
Safety Statements: 17 · 17-26-36/37/39-45
RIDADR: 3084 · UN 3084 8/PG 2
WGK Germany: 3 · 3
F: 3 · 3
TSCA: Yes
HS Code: 2811 · 2811 19 80
HazardClass: 5.1 · 5.1
PackingGroup: III
Storage Class: 5.1 B · 5.1B - Oxidizing hazardous materials
Hazard Classifications: 1 Ox · Eye Dam. 1Ox. Sol. 3Skin Corr. 1B
Limited Quantities: 1 Kg · 1 Kg (2.2 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Safety & regulation

Safety data

F: 3
PPE: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk: 3
tsca: Yes
ridadr: UN 3084 8/PG 2
hs_code: 2811 19 80
risk_code: 8-34
Signal word: Danger
Symbol(GHS): GHS03,GHS05
hazard_code: O,C
safety_code: 17-26-36/37/39-45
hazard_class: 5.1
Storage Class: 5.1B - Oxidizing hazardous materials
packing_group: III
Hazard statements: H272-H314
Limited Quantities: 1 Kg (2.2 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Hazard Classifications: Eye Dam. 1Ox. Sol. 3Skin Corr. 1B
Precautionary statements: P210-P220-P260-P280-P303+P361+P353-P305+P351+P338

Chemistry & industry

Applications · 4 items

UsesPhosphomolybdic Acid is a reagent used for spectrophotometric determination of phosphate ions.

UsesPhosphomolybdic acid hydrate may be used in the synthesis of molybdenum disulfide (MoS2)-reduced graphene oxide (RGO) composites with potential application as electrodes for sodium ion battery. It may also be used as a catalyst precursor in the presence of hydrogen peroxide as oxidant for the dibenzothiophenes oxidation in diesel fuels.

UsesReactant for preparation of:Catalysts for the nitration of aromatic compoundsHighly dispersed MoOx/CNTs (carbon nanotubes) as a support for Pt catalystsReduced molybdophosphate mixed-valence Keggin clustersPolyoxometalate (POM) hybrid materials based on Keggin polyanion building blocksLuminescent Langmuir-Blodgett filmsAnchored Wilkinson catalyst

General DescriptionPhosphomolybdic acid hydrate (PAH) is yellow and crystallisable compound. It precipitates from potash, oxides of rubidium, caesium and thallium, ammonia and other nitrogenous organic alkaloids.

Upstream & downstream products

Upstream raw materials

Phosphoric acid Diethyl ether

Suppliers50 total

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科瑞迪化学400-821-5857 021-64326257 · [email protected]

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