HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nickel;perchloric acid;hydrate
Reag · ent g · (II) perchL · rade NickeL · orate hexahydrate · Reagent Grade NickeL · NICKEL (II) PERCHLORATE · Nickel(II)perchlorate6H2O
Identifiers & Physical Properties
| CAS No. | 13520-61-1 |
|---|---|
| Molecular formula | ClH3NiO5 |
| Average molar mass | 177.17 g/mol |
| Monoisotopic mass | 175.902243 g/mol |
| SMILES | O.[Ni].[O-][Cl+3]([O-])([O-])O |
| InChIKey | BOUCBOLTHQZUOK-UHFFFAOYSA-N |
| PubChem CID | 16211971 |
Chemical & Physical Properties
| Topological polar surface area | 72.4 |
|---|---|
| Hydrogen bond donors | 2 |
| Hydrogen bond acceptors | 5 |
| Rotatable bonds | 0 |
| Heavy atoms | 7 |
| Formal charge | 0 |
| Complexity | 114 |
| Melting point | 140 °C(lit.) |
| Refractive index | 1.55 |
| Storage conditions | 2-8°C, protect from light, stored under nitrogen |
| Physical state | Damp Crystalline Solid |
| Color | Green |
| Solubility | Very soluble in water. Soluble in many organic solvents |
| Sensitivity | Hygroscopic |
| Exposure limits | ACGIH: TWA 0.1 mg/m3NIOSH: IDLH 10 mg/m3TWA 0.015 mg/m3 |
| Stability | hygroscopic |
| Major applications | battery precursorscatalystsmaterial synthesis precursor |
| InChI | 1S/2ClHO4.Ni.6H2O/c2*2-1(3,4)5/h2*(H,2,3,4,5)6*1H2/q+2/p-2 |
| InChIKey | WHGYCGOFTBFDLW-UHFFFAOYSA-L |
| SMILES | O.O.O.O.O.O.[Ni++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O |
| CAS DataBase Reference | 13520-61-1(CAS DataBase Reference) |
| UNSPSC Code | 12352302 |
| NACRES | NA.23 |
| GHS pictogram | GHS03,GHS05,GHS08,GHS09 |
| Signal word | Danger |
| GHS hazard statements | H272-H314-H317-H334-H341-H350-H360-H372-H410 |
| GHS precautionary statements | P210-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Personal protective equipment (PPE) | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges |
| Hazard symbols | O,T,N |
| Risk statements (R) | 49-8-36/38-43-68-50/53-48/23-42/43-34-61 |
| Safety statements (S) | 53-16-26-36/37/39-45-61-60 |
| UN transport number | UN 1481 5.1/PG 2 |
| Water hazard class (WGK) | 3 |
| RTECS number | SC9550000 |
| TSCA inventory status | Yes |
| Hazard class | 5.1Aquatic Acute 1Aquatic Chronic 1Carc. 1AEye Dam. 1Muta. 2Ox. Sol. 3Repr. 1BResp. Sens. 1Skin Corr. 1BSkin Sens. 1STOT RE 1 |
| Packing group | II |
| Storage class | 5.1A - Strongly oxidizing hazardous materials |
Safety & Regulations
| Personal protective equipment (PPE) | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges |
|---|---|
| Water hazard class (WGK) | 3 |
| TSCA inventory status | Yes |
| RTECS number | SC9550000 |
| UN transport number | UN 1481 5.1/PG 2 |
| Risk statements (R) | 49-8-36/38-43-68-50/53-48/23-42/43-34-61 |
| Signal word | Danger |
| GHS pictogram | GHS03,GHS05,GHS08,GHS09 |
| Hazard symbols | O,T,N |
| Safety statements (S) | 53-16-26-36/37/39-45-61-60 |
| Hazard class | 5.1Aquatic Acute 1Aquatic Chronic 1Carc. 1AEye Dam. 1Muta. 2Ox. Sol. 3Repr. 1BResp. Sens. 1Skin Corr. 1BSkin Sens. 1STOT RE 1 |
| Storage class | 5.1A - Strongly oxidizing hazardous materials |
| Packing group | II |
| GHS hazard statements | H272-H314-H317-H334-H341-H350-H360-H372-H410 |
| GHS precautionary statements | P210-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
Applications & Uses
Uses
Nickel(II) perchlorate hexahydrate is used as a starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.
Uses
Nickel(II) perchlorate hexahydrate may be used in the synthesis of tris(2,2′-bipyridylamine)nickel(II) perchlorate and 4,7,7-trimethyl-3,4,5,6,7,8-hexahydrobenzopyran-2(H),5-dione.
General Description
Nickel(II) perchlorate hexahydrate is a hydrated nickel(II) salt.