Chloro(1,5-hexadiene)rhodium(I) Dimer

HCID 169482

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Basic information

CAS: 32965-49-4
Standard SMILES: C=CCCC=C.C=CCCC=C.[Cl-].[Cl-].[Rh].[Rh]
InChIKey: HXNWPVBAYNUADR-UHFFFAOYSA-L
Molecular formula: C12H20Cl2Rh2-2
Average molar mass: 441 g/mol
Monoisotopic mass: 439.90519

Names & identifiers

Preferred name: Chloro(1,5-hexadiene)rhodium(I) Dimer
IUPAC: bis(hexa-1,5-diene);bis(rhodium);dichloride
English name: Chloro(1,5-hexadiene)rhodium(I) dimer
Molecular formula: C12H20Cl2Rh2
Molecular weight: 441

Names & synonyms

CHLORO(1,5-HEXADIENE)RHODIUM(I) DIMERRefChem:575691803-662-632965-49-4Chloro(1,5-hexadiene)rhodium(I),dimerhexa-1,5-diene;rhodium;dichlorideMFCD00064595Di-mu-chlorobis((1,2,5,6-eta)1,5-hexadiene)dirhodiumC12H20Cl2Rh2C12H20Cl2Rh2--SCHEMBL29741437KPWHMEFNDAMNKW-UHFFFAOYSA-L

Show more names

Dichlorobis(1,5-hexadiene)dirhodiumChloro(1,5-hexadiene) rhodium dimerChloro(1,5-hexadiene)rhodium(I),dimer 98%CHLORO(1,5-HEXADIENE)RHODIUM(I) DIMER, 9 8%di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodiumRhodium, di-m-chlorobis[(1,2,5,6-h)-1,5-hexadiene]di-DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-HEXADIENE]DIRHODIUMDi-mu-chlorobis[(1,2,5,6-eta)-1,5-hexadiene]dirhodium(I)

SY104361Rhodium, di-mu-chlorobis((1,2,5,6-eta)1,5-hexadiene)di-

Database identifiers

CAS: 32965-49-4

Properties

Computed structural properties

Topological polar surface area: 0 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 2
Rotatable bonds: 6
Heavy atoms: 16
Formal charge: -2
Complexity: 36

Physicochemical properties

Melting point: 118 · 118-120 °C
storage temp.: 2 · under inert gas (nitrogen or Argon) at 2-8°C
form: Crystalline Powder
color: Gold
InChI: 1S/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/q;;;;2*+1/p-2
InChIKey: HXNWPVBAYNUADR-UHFFFAOYSA-L
SMILES: Cl[Rh].Cl[Rh].C=CCCC=C.C=CCCC=C
UNSPSC Code: 12161600 · 12161600
NACRES: 22 · NA.22
Symbol(GHS): 5 · GHS05,GHS07
Signal word: Danger
Hazard statements: 315 · H315-H318-H335
Precautionary statements: 261 · P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs: Respiratory system
Hazard Codes: Xi
Risk Statements: 36 · 36/37/38

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 4 items

Danger

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P354+P338, P317, P319, P321, P332+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

Safety data

wgk: 3
tsca: No
hs_code: 28439000
risk_code: 36/37/38
Signal word: Danger
Symbol(GHS): GHS05,GHS07
hazard_code: Xi
safety_code: 37/39-26-36/37/39-27
Storage Class: 11 - Combustible Solids
target organs: Respiratory system
Hazard statements: H315-H318-H335
Hazard Classifications: Eye Dam. 1Skin Irrit. 2STOT SE 3
Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338

Chemistry & industry

Applications

UsesCatalyst for:HydrogenationEnantioselective hydrosilylation

Suppliers67 total

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]

清宁生物（江苏博泉生物科技有限公司）王 19352250998 13160238781 · [email protected]

上海仲因实业有限公司2537653158 16621191650 · [email protected]

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Compound notes

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